Technology Process of C41H53BrClN3O12Si
There total 17 articles about C41H53BrClN3O12Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
tetrabutyl ammonium fluoride; acetic acid;
In
tetrahydrofuran;
at 25 ℃;
for 1h;
DOI:10.1021/ja209937s
- Guidance literature:
-
C41H55BrN4O12Si;
With
tetrafluoroboric acid;
In
acetonitrile;
at 0 ℃;
for 0.166667h;
With
tert.-butylnitrite;
In
acetonitrile;
at 0 ℃;
for 0.166667h;
With
copper(l) chloride; copper dichloride;
In
water; acetonitrile;
at 0 - 25 ℃;
for 1h;
Product distribution / selectivity;
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 98 percent / H2 / Raney-Ni / methanol / 5 h / 0 °C
2.1: 100 percent / aq. LiOH / tetrahydrofuran / 2 h / 0 °C
3.1: 70 percent / NaHCO3; DEPBT / dimethylformamide / 8 h / 0 - 25 °C
4.1: 60 percent / K2CO3; CaCO3; 3 Angstroem molecular sieves / tetrahydrofuran / 72 h / -20 - 75 °C
5.1: H2 / Raney-Ni / methanol / 2 h / 0 °C
6.1: HBF4; t-BuONO / acetonitrile / 0.17 h / 0 °C
6.2: 3.8 mg / CuCl; aq. CuCl2 / acetonitrile / 0 - 25 °C
With
lithium hydroxide; tetrafluoroboric acid; tert.-butylnitrite; 3 A molecular sieve; hydrogen; sodium hydrogencarbonate; potassium carbonate; 3-[(diethoxyphosphinyl)oxy]-1,2,3-benzotriazin-4(3H)-one; calcium carbonate;
nickel;
In
tetrahydrofuran; methanol; N,N-dimethyl-formamide; acetonitrile;
6.2: Sandmayer reaction;
DOI:10.1021/ja0572912
