(Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine

Base Information

Chemical Name:(Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine
CAS No.:1443365-66-9
Molecular Formula:C₂₂H₃₅NO₃SSi
Molecular Weight:421.676
Hs Code.:

Synonyms:(Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine

Suppliers and Price of (Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine

There total 4 articles about (Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1121746-86-8
N-(but-3-en-1-yl)-N-(5-((tert-butyldimethylsilyl)oxy)pent-1-yn-1-yl)-4-methylbenzenesulfonamide

: 1443365-66-9
(Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine

Guidance literature:: With N,N'-bis(benzyliden)ethylendiamine; palladium diacetate; In toluene; at 60 ℃; for 0.5h; Reagent/catalyst; Solvent; Time; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201304186

Reference yield: 83.0%

: 1361582-82-2
N-(3-bromobut-3-en-1-yl)-N-(5-((tert-butyldimethylsilyl)oxy)pent-1-yn-1-yl)-4-methylbenzenesulfonamide

: 1443365-66-9
(Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In ethanol; at 80 ℃; for 1h;
DOI:10.1002/adsc.201200703

Reference yield:

: 1361583-02-9
N-(3-bromobut-3-en-1-yl)-4-methylbenzenesulfonamide

: 1443365-66-9
(Z)-2-(4-((tert-butyldimethylsilyl)oxy)butylidene)-3-methylene-1-tosylpyrrolidine

Guidance literature:: Multi-step reaction with 2 steps

1: 1,10-Phenanthroline; potassium phosphate; copper(ll) sulfate pentahydrate / toluene / 16 h / 70 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate / ethanol / 1 h / 80 °C

With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 1,10-Phenanthroline; copper(ll) sulfate pentahydrate; caesium carbonate; In ethanol; toluene;
DOI:10.1002/adsc.201200703