{Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆

Base Information

Chemical Name:{Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆
CAS No.:89509-87-5
Molecular Formula:C₄₄H₃₆F₆IrP₂*F₆Sb
Molecular Weight:1168.67
Hs Code.:

{Ir(cycloocta-1,5-diene)((p-FC<sub>6</sub>H<sub>4</sub>)3P)2}SbF<sub>6</sub>

Synonyms:{Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆

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Chemical Property of {Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆

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Technology Process of {Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆

There total 1 articles about {Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 89529-62-4
dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate

: 292-64-8
Cyclooctan

: 89509-87-5
{Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆

Guidance literature:: With tert-butylethylene; In neat (no solvent); t-BuCH=CH2 to Ir-complex ratio 4:1, neat alkane as solvent, 125°C, 18 h;

Reference yield: 91.0%

: 89509-87-5
{Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆

: 89529-62-4
dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate

Guidance literature:: With hydrogen; acetone; In acetone; H2 was bubbled through a vigorously stirred acetone soln. of the Ir-complex at 0°C for 20 min; concd., Et2O and pentane were added, ppt. was recrystd. from CH2Cl2-Me2CO under H2 with Et2O-pentane; elem. anal.;
DOI:10.1021/om00147a003

Reference yield: 90.0%

: 89509-87-5
{Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆

: dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluorophosphate

Guidance literature:: With hydrogen; In acetone; soln. of Ir complex was vigorously stirred under H2 (1 atm) at 0°C for 30 min, SbF6 salt was pptd. by addn. of Et2O and pentane, filtered off and washed with pentane, dissolved in CH2Cl2/acetone and stirred under H2 for 5 min; pptn. with Et2O/pentane; elem. anal.;
DOI:10.1021/ja00260a013