dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate

Base Information

• Chemical Name: dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate
• CAS No.: 89529-62-4
• Molecular Formula: C₄₂H₃₈F₆IrO₂P₂*F₆Sb
• Molecular Weight: 1178.66

Synonyms:dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate

Chemical Property of dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate

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Technology Process of dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate

There total 1 articles about dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

{Ir(cycloocta-1,5-diene)((p-FC6H4)3P)2}SbF6 (89509-87-5) → dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate (89529-62-4)

Guidance literature:

With hydrogen; acetone; In acetone; H2 was bubbled through a vigorously stirred acetone soln. of the Ir-complex at 0°C for 20 min; concd., Et2O and pentane were added, ppt. was recrystd. from CH2Cl2-Me2CO under H2 with Et2O-pentane; elem. anal.;

DOI:10.1021/om00147a003

Reference yield: 95.0%

dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate (89529-62-4) + 5,5-dimethyl-cyclopenta-1,3-diene (4125-18-2) → bis(tris(p-fluorophenyl)phosphine)(5,5-dimethylcyclopentadiene)iridium(I) hexafluoroantimonate * 2.5 CH2Cl2 * (C2H5)2O

Guidance literature:

With CH₂Cl₂; (C₂H₅)2O; In neat (no solvent); freeing from air by freeze-thaw cycling; heating for 2 h at 85°C; removing the volatiles; recrystn. from CH2Cl2/Et2O; elem. anal.;

DOI:10.1021/ja00283a015

Reference yield: 90.0%

dihydridobis(acetone)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate (89529-62-4) + 1-ethylcyclopentene (2146-38-5) → hydrido(η-ethylcyclopentadienyl)bis(tris(p-fluorophenyl)phosphine)iridium(III) hexafluoroantimonate

Guidance literature:

In neat (no solvent); freeing from air by freeze-thaw cycling; heating for 2 h at 85°C; removing the volatiles; recrystn. from CH2Cl2/Et2O;

DOI:10.1021/ja00283a015

upstream raw materials:

{Ir(cycloocta-1,5-diene)((p-FC₆H₄)3P)2}SbF₆

Downstream raw materials:

Ir(C₅H₅)(P(C₆H₄F)3)2H⁽¹⁺⁾*SbF₆^(1-) = [Ir(C₅H₅)(P(C₆H₄F)3)2H][SbF₆]

(η6-benzene)bis(triphenylphosphine)iridium(I) hexafluoroantimonate

{(η5-cyclohexadienyl)IrH(PPh3)2}SbF6

C₄₂H₃₀F₆IrP₂⁽¹⁺⁾

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