N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide

Base Information

Chemical Name:N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide
CAS No.:1486515-49-4
Molecular Formula:C₂₈H₃₃NO₃SSi
Molecular Weight:491.726
Hs Code.:

Synonyms:N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide

Suppliers and Price of N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide

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Technology Process of N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide

There total 2 articles about N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1-bromo-4-(tert-butyl-diphenyl-silanyloxy)-but-1-yne

: 640-61-9
N-methyl-p-toluenesulfonylamide

: 1486515-49-4
N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide

Guidance literature:: With 1,10-Phenanthroline; potassium carbonate; copper(II) sulfate; In water; toluene; at 80 ℃;
DOI:10.1021/ol4031028

Reference yield:

: 88158-68-3
4-(tert-butyldiphenylsilyloxy)-1-butyne

: 1486515-49-4
N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide

Guidance literature:: Multi-step reaction with 2 steps

1: silver nitrate; N-Bromosuccinimide / acetone / 20 °C

2: potassium carbonate; copper(II) sulfate; 1,10-Phenanthroline / toluene; water / 80 °C

With N-Bromosuccinimide; 1,10-Phenanthroline; potassium carbonate; silver nitrate; copper(II) sulfate; In water; acetone; toluene;
DOI:10.1021/ol4031028

Reference yield: 71.0%

: 1486515-49-4
N-[4-(tert-butyldiphenylsilyloxy)but-1-yn-1-yl]-N-methyltosylamide

: 688-73-3
tri-n-butyl-tin hydride

: 1486515-52-9
C₄₀H₆₁NO₃SSiSn

Guidance literature:: With tris(t-butyl isocyanide)tricarbonylmolybdenum(O); carbon monoxide; hydroquinone; In tetrahydrofuran; at 55 ℃; stereoselective reaction; Schlenk technique;
DOI:10.1021/ol4031028