methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate

Base Information

Chemical Name:methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate
CAS No.:87326-43-0
Molecular Formula:C₂₄H₂₈O₇
Molecular Weight:428.482
Hs Code.:

Synonyms:methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate

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Chemical Property of methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate

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Technology Process of methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate

There total 9 articles about methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 93382-48-0
allyl 4,6-O-benzylidene-α-D-glucopyranoside

: 87326-43-0
methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate

Guidance literature:: Multi-step reaction with 8 steps

1: 71 percent / sodium hydride / dimethylformamide / 0 °C

2: 100 percent / toluene-p-sulfonic acid / H₂O; methanol / 2 h / 80 °C

3: pyridine / 2 h / 80 °C

4: 80 °C / Heating

5: 24 g / aq. 80percent acetic acid / CH₂Cl₂ / Ambient temperature

6: 25 g / chromium trioxide, 3.5M sulfuric acid / acetone / 5 h / Ambient temperature

7: 19 g / 6M sodium hydroxide / methanol / 3 h / Ambient temperature

8: 15.8 g / diethyl ether

With pyridine; chromium(VI) oxide; sodium hydroxide; sulfuric acid; sodium hydride; toluene-4-sulfonic acid; acetic acid; In methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0008-6215(00)90633-5

Reference yield:

: 100-39-0
benzyl bromide

: 87326-43-0
methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate

Guidance literature:: Multi-step reaction with 8 steps

1: 71 percent / sodium hydride / dimethylformamide / 0 °C

2: 100 percent / toluene-p-sulfonic acid / H₂O; methanol / 2 h / 80 °C

3: pyridine / 2 h / 80 °C

4: 80 °C / Heating

5: 24 g / aq. 80percent acetic acid / CH₂Cl₂ / Ambient temperature

6: 25 g / chromium trioxide, 3.5M sulfuric acid / acetone / 5 h / Ambient temperature

7: 19 g / 6M sodium hydroxide / methanol / 3 h / Ambient temperature

8: 15.8 g / diethyl ether

With pyridine; chromium(VI) oxide; sodium hydroxide; sulfuric acid; sodium hydride; toluene-4-sulfonic acid; acetic acid; In methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; acetone;
DOI:10.1016/S0008-6215(00)90633-5

Reference yield:

: 87326-32-7
allyl 2,3-di-O-benzyl-α-D-glucopyranoside

: 87326-43-0
methyl (allyl 2,3-di-O-benzyl-α-D-glucopyranosid)uronate

Guidance literature:: Multi-step reaction with 6 steps

1: pyridine / 2 h / 80 °C

2: 80 °C / Heating

3: 24 g / aq. 80percent acetic acid / CH₂Cl₂ / Ambient temperature

4: 25 g / chromium trioxide, 3.5M sulfuric acid / acetone / 5 h / Ambient temperature

5: 19 g / 6M sodium hydroxide / methanol / 3 h / Ambient temperature

6: 15.8 g / diethyl ether

With pyridine; chromium(VI) oxide; sodium hydroxide; sulfuric acid; acetic acid; In methanol; diethyl ether; dichloromethane; acetone;
DOI:10.1016/S0008-6215(00)90633-5