1,2,6,7-tetraethyl-4,4-difluoro-8-(p-hydroxyphenyl)-3,5-dimethyl-4-bora-3a,4a-diaza-s-indacene

Base Information

Chemical Name:1,2,6,7-tetraethyl-4,4-difluoro-8-(p-hydroxyphenyl)-3,5-dimethyl-4-bora-3a,4a-diaza-s-indacene
CAS No.:1254253-64-9
Molecular Formula:C₂₅H₃₁BF₂N₂O
Molecular Weight:424.342
Hs Code.:

Synonyms:1,2,6,7-tetraethyl-4,4-difluoro-8-(p-hydroxyphenyl)-3,5-dimethyl-4-bora-3a,4a-diaza-s-indacene

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Chemical Property of 1,2,6,7-tetraethyl-4,4-difluoro-8-(p-hydroxyphenyl)-3,5-dimethyl-4-bora-3a,4a-diaza-s-indacene

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Technology Process of 1,2,6,7-tetraethyl-4,4-difluoro-8-(p-hydroxyphenyl)-3,5-dimethyl-4-bora-3a,4a-diaza-s-indacene

There total 2 articles about 1,2,6,7-tetraethyl-4,4-difluoro-8-(p-hydroxyphenyl)-3,5-dimethyl-4-bora-3a,4a-diaza-s-indacene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 1267502-26-0
(HO)C₆H₄CH(C₄(CH₃)(C₂H₅)2NH)2

: 1254253-64-9
1,2,6,7-tetraethyl-4,4-difluoro-8-(p-hydroxyphenyl)-3,5-dimethyl-4-bora-3a,4a-diaza-s-indacene

Guidance literature:: (HO)C₆H₄CH(C₄(CH₃)(C₂H₅)2NH)2; With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; for 1h;

With triethylamine; In dichloromethane; for 0.166667h;

With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/ic1016092

Reference yield: 42.0%

: 1267502-26-0
(HO)C₆H₄CH(C₄(CH₃)(C₂H₅)2NH)2

: 109-63-7
boron trifluoride diethyl etherate

: 1254253-64-9
1,2,6,7-tetraethyl-4,4-difluoro-8-(p-hydroxyphenyl)-3,5-dimethyl-4-bora-3a,4a-diaza-s-indacene

Guidance literature:: With 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; (C₂H₅)3N; In dichloromethane; hydroxyphenyldipyrromethane was dissolved in CH2Cl2, oxidized with DDQ at room temp. for 1 h, Et3N was added, stirred for 10 min, BF3*Et2O was added, stirred at room temp. for 1 h; diluted with CH2Cl2, washed with 0.1 M aq. soln. of NaOH, dried over Na2SO4, filtered, evapd. in vac., column chromy. (silica, petroleum ether/EtOAc, 85:15);
DOI:10.1021/ic1016092