Methyl 5-(bromomethyl)-2-nitrobenzoate

Base Information

Chemical Name:Methyl 5-(bromomethyl)-2-nitrobenzoate
CAS No.:88071-91-4
Molecular Formula:C9H8 Br N O4
Molecular Weight:274.071
Hs Code.:2916399090
DSSTox Substance ID:DTXSID90539430
Wikidata:Q82415177
Mol file:88071-91-4.mol

Synonyms:Methyl 5-(bromomethyl)-2-nitrobenzoate;88071-91-4;methyl 5-bromomethyl-2-nitrobenzoate;Benzoic acid,5-(bromomethyl)-2-nitro-, methyl ester;MFCD20528191;SCHEMBL147719;DTXSID90539430;AJAFGSCUXQKJRK-UHFFFAOYSA-N;AKOS037649645;Methyl5-(bromomethyl)-2-nitrobenzoate;3-methoxycarbonyl 4-nitrobenzyl bromide;3-Methoxycarbonyl-4-nitrobenzyl bromide;CS-12854;SY226903;5-bromomethyl-2-nitrobenzoic acid methyl ester;EN300-215381;5-bromomethyl-2-nitro-benzoic acid methyl ester;A915957

Suppliers and Price of Methyl 5-(bromomethyl)-2-nitrobenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Ambeed
Methyl5-(bromomethyl)-2-nitrobenzoate 98%
1g
$ 46.00

Ambeed
Methyl5-(bromomethyl)-2-nitrobenzoate 98%
250mg
$ 19.00

Ambeed
Methyl5-(bromomethyl)-2-nitrobenzoate 98%
5g
$ 168.00

Alichem
Methyl5-bromomethyl-2-nitrobenzoate
1g
$ 1445.30

Alichem
Methyl5-bromomethyl-2-nitrobenzoate
500mg
$ 806.85

Alichem
Methyl5-bromomethyl-2-nitrobenzoate
250mg
$ 499.20

AK Scientific
Methyl5-(bromomethyl)-2-nitrobenzoate
250mg
$ 107.00

Total 9 raw suppliers

Chemical Property of Methyl 5-(bromomethyl)-2-nitrobenzoate

Chemical Property:

PSA：72.12000
LogP:2.79950
XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:272.96367
Heavy Atom Count:15
Complexity:253

Purity/Quality:

99%, ^*data from raw suppliers

Methyl5-(bromomethyl)-2-nitrobenzoate 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=C(C=CC(=C1)CBr)[N+](=O)[O-]

Technology Process of Methyl 5-(bromomethyl)-2-nitrobenzoate

There total 2 articles about Methyl 5-(bromomethyl)-2-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 20587-30-8
5-methyl-2-nitro-benzoic acid methyl ester

: 88071-91-4
5-bromomethyl-2-nitrobenzoic acid methyl ester

Guidance literature:: With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In benzene; Heating / reflux;

Reference yield:

: 3113-72-2
5-methyl-2-nitrobenzoic acid

: 88071-91-4
5-bromomethyl-2-nitrobenzoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 84.5 percent / HCl / 5 h / Heating

2: 33.8 percent / N-bromosuccinimide; benzoyl peroxide / CHCl₃ / 24 h

With hydrogenchloride; N-Bromosuccinimide; dibenzoyl peroxide; In chloroform;
DOI:10.1016/j.bmc.2005.11.006