1,2,4,6-TETRA-O-ACETYL-3-DEOXY-3-FLUORO-BETA-D-GLUCOPYRANOSE

Base Information

Chemical Name:1,2,4,6-TETRA-O-ACETYL-3-DEOXY-3-FLUORO-BETA-D-GLUCOPYRANOSE
CAS No.:83602-93-1
Molecular Formula:C₁₄H₁₉FO₉
Molecular Weight:350.298
Hs Code.:2940000080
Mol file:83602-93-1.mol

Synonyms:D-Glucopyranose,3-deoxy-3-fluoro-, tetraacetate (9CI);1,2,4,6-Tetra-O-acetyl-3-deoxy-3-fluoro-D-glucopyranose

Suppliers and Price of 1,2,4,6-TETRA-O-ACETYL-3-DEOXY-3-FLUORO-BETA-D-GLUCOPYRANOSE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1,2,4,6-TETRA-O-ACETYL-3-DEOXY-3-FLUORO-BETA-D-GLUCOPYRANOSE 95.00%
5MG
$ 505.89

Total 4 raw suppliers

Chemical Property of 1,2,4,6-TETRA-O-ACETYL-3-DEOXY-3-FLUORO-BETA-D-GLUCOPYRANOSE

Chemical Property:

Melting Point:116 - 120 °C
PSA：114.43000
LogP:0.03900

Purity/Quality:

95% ^*data from raw suppliers

1,2,4,6-TETRA-O-ACETYL-3-DEOXY-3-FLUORO-BETA-D-GLUCOPYRANOSE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1,2,4,6-TETRA-O-ACETYL-3-DEOXY-3-FLUORO-BETA-D-GLUCOPYRANOSE

There total 8 articles about 1,2,4,6-TETRA-O-ACETYL-3-DEOXY-3-FLUORO-BETA-D-GLUCOPYRANOSE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 7226-70-2
(3S,4S,5R,6R)-4-fluoro-6-(hydroxymethyl)tetrahydro-2H-pyran-2,3,5-triol

: 108-24-7
acetic anhydride

: 7226-43-9,20409-32-9,22434-91-9,22434-92-0,88198-26-9,83602-93-1
[(2R,3R,4S,5S)-3,5,6-triacetoxy-4-fluoro-tetrahydropyran-2-yl]methyl acetate

Guidance literature:: With pyridine; at 20 ℃;

Reference yield: 61.0%

: 14049-05-9
3-deoxy-1,2;5,6-di-O-isopropylidene-3-fluoro-α-D-glucofuranose

: 108-24-7
acetic anhydride

: 7226-43-9,20409-32-9,22434-91-9,22434-92-0,88198-26-9,83602-93-1
[(2R,3R,4S,5S)-3,5,6-triacetoxy-4-fluoro-tetrahydropyran-2-yl]methyl acetate

Guidance literature:: 3-deoxy-1,2;5,6-di-O-isopropylidene-3-fluoro-α-D-glucofuranose; With trifluoroacetic acid; In water; acetic acid; at 20 ℃;

acetic anhydride; With pyridine; Further stages.;
DOI:10.1016/j.carres.2008.01.031

Reference yield: 60.0%

: 14049-05-9
3-deoxy-1,2;5,6-di-O-isopropylidene-3-fluoro-α-D-glucofuranose

: 127-09-3
sodium acetate

: 108-24-7
acetic anhydride

: 7226-43-9,20409-32-9,22434-91-9,22434-92-0,88198-26-9,83602-93-1
[(2R,3R,4S,5S)-3,5,6-triacetoxy-4-fluoro-tetrahydropyran-2-yl]methyl acetate

Guidance literature:: 3-deoxy-1,2;5,6-di-O-isopropylidene-3-fluoro-α-D-glucofuranose; With trifluoroacetic acid; In tetrahydrofuran; water; at 20 ℃; for 14h;

sodium acetate; acetic anhydride; for 0.5h; Reflux;