3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin

Base Information

Chemical Name:3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin
CAS No.:172832-34-7
Molecular Formula:C₂₀H₃₁NO₂S₂Si
Molecular Weight:409.689
Hs Code.:

Synonyms:3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin

Suppliers and Price of 3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin

There total 5 articles about 3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.1%

: 165404-83-1
3-[(tert-butyldimethylsilyloxy)methyl]-6-(hydroxymethyl)-1,2-dithiin

: 99-07-0
3-Dimethylaminophenol

: 1972-28-7,218603-74-8
diethylazodicarboxylate

: 172832-34-7
3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin

Guidance literature:: With triphenylphosphine; In tetrahydrofuran;

Reference yield:

: 2,5-bis<(2-cyanoethyl)thio>-2,4-hexadiene-1,6-diol

: 172832-34-7
3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin

Guidance literature:: Multi-step reaction with 3 steps

1: 49.3 percent / imidazole / dimethylformamide / 16 h / Ambient temperature

2: 1.) t-BuOK, 2.) aq. K₃FeCN₆ / 1.) eter, 11 min, 2.) eter, 12 min

3: triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran

With 1H-imidazole; potassium tert-butylate; triphenylphosphine; potassium hexacyanoferrate(III); diethylazodicarboxylate; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jm00014a016

Reference yield:

: 1-<(tert-butyldimethylsilyl)oxy>-2,5-bis<(2-cyanoethyl)thio>-2,4-hexadien-6-ol

: 172832-34-7
3-[(tert-butyldimethylsilyloxy)methyl]-6-[[3-(N,N-dimethylamino)-phenyloxy]methyl]-1,2-dithiin

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) t-BuOK, 2.) aq. K₃FeCN₆ / 1.) eter, 11 min, 2.) eter, 12 min

2: triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran

With potassium tert-butylate; triphenylphosphine; potassium hexacyanoferrate(III); diethylazodicarboxylate; In tetrahydrofuran;
DOI:10.1021/jm00014a016