ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate

Base Information

Chemical Name:ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate
CAS No.:1454915-74-2
Molecular Formula:C₁₇H₃₀O₃Si
Molecular Weight:310.509
Hs Code.:

Synonyms:ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate

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Chemical Property of ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate

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Technology Process of ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate

There total 3 articles about ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 1454915-73-1
ethyl 2-((1R,2S,6S)-2-hydroxy-3-methyl-6-(prop-1-en-2-yl)cyclohex-3-en-1-yl)acetate

: 1454915-74-2
ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;
DOI:10.1039/c3cc45170d

Reference yield:

: 1454915-72-0
ethyl 2-((1R,6S)-3-methyl-2-oxo-6-(prop-1-en-2-yl)cyclohex-3-en-1-yl)acetate

: 1454915-74-2
ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate

Guidance literature:: Multi-step reaction with 2 steps

1: cerium(III) chloride heptahydrate; sodium tetrahydroborate / methanol / -78 - -30 °C / Inert atmosphere

2: triethylamine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

With sodium tetrahydroborate; cerium(III) chloride heptahydrate; triethylamine; In methanol; dichloromethane;
DOI:10.1039/c3cc45170d

Reference yield:

: 2244-16-8,6485-40-1
(S)-p-mentha-6,8-dien-2-one

: 1454915-74-2
ethyl 2-((1R,2S,6S)-3-methyl-6-(prop-1-en-2-yl)-2-((trimethylsilyl)oxy)cyclohex-3-en-1-yl) acetate

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: cerium(III) chloride heptahydrate; sodium tetrahydroborate / methanol / -78 - -30 °C / Inert atmosphere

3.1: triethylamine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

With sodium tetrahydroborate; cerium(III) chloride heptahydrate; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1039/c3cc45170d