methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate

Base Information

Chemical Name:methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate
CAS No.:1426667-62-0
Molecular Formula:C₂₁H₁₄FN₅O₃
Molecular Weight:403.372
Hs Code.:

Synonyms:methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate

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Chemical Property of methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate

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Technology Process of methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate

There total 7 articles about methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.3%

: 1426663-95-7
methyl (3-(2-fluoro-4-hydroxyphenyl)-3,4-dihydro-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate

: 1426667-62-0
methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate

Guidance literature:: With 2,3,5,6-tetrachlorocyclohexa-2,5-diene-1,4-dione; In benzene; for 60h; Reflux;

Reference yield:

: 1426663-88-8
methyl (4-(2-aminophenyl)pyrrolo[2,1-f][1,2,4]triazin-2-yl)carbamate

: 1426667-62-0
methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate

Guidance literature:: Multi-step reaction with 2 steps

1: sulfuric acid / methanol / 2 h / Reflux

2: 2,3,5,6-tetrachlorocyclohexa-2,5-diene-1,4-dione / benzene / 60 h / Reflux

With 2,3,5,6-tetrachlorocyclohexa-2,5-diene-1,4-dione; sulfuric acid; In methanol; benzene;

Reference yield:

: 628733-99-3
ethyl 1-amino-1H-pyrrole-2-carboxylate

: 1426667-62-0
methyl (3-(2-fiuoro-4-hydroxyphenyl)-4,9,11,11a-tetraazadibenzo[cd,f]azulen-10-yl)carbamate

Guidance literature:: Multi-step reaction with 6 steps

1: acetic acid / methanol / 16 h / 20 °C

2: sodium methylate / methanol / 16 h / 20 °C

3: N-benzyl-N,N,N-triethylammonium chloride; N,N-diethylaniline; trichlorophosphate / acetonitrile / 15 h / 80 °C

4: bis-triphenylphosphine-palladium(II) chloride; sodium carbonate / water; N,N-dimethyl-formamide / 2 h / 80 °C / Inert atmosphere

5: sulfuric acid / methanol / 2 h / Reflux

6: 2,3,5,6-tetrachlorocyclohexa-2,5-diene-1,4-dione / benzene / 60 h / Reflux

With bis-triphenylphosphine-palladium(II) chloride; 2,3,5,6-tetrachlorocyclohexa-2,5-diene-1,4-dione; sulfuric acid; N-benzyl-N,N,N-triethylammonium chloride; sodium methylate; sodium carbonate; acetic acid; N,N-diethylaniline; trichlorophosphate; In methanol; water; N,N-dimethyl-formamide; acetonitrile; benzene;