mer,trans-Re(CO)3(PPh₃)2CHO

Base Information

Chemical Name:mer,trans-Re(CO)3(PPh₃)2CHO
CAS No.:118228-22-1
Molecular Formula:C₄₀H₃₁O₄P₂Re
Molecular Weight:823.838
Hs Code.:

Synonyms:mer,trans-Re(CO)3(PPh₃)2CHO

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Chemical Property of mer,trans-Re(CO)3(PPh₃)2CHO

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Technology Process of mer,trans-Re(CO)3(PPh₃)2CHO

There total 2 articles about mer,trans-Re(CO)3(PPh₃)2CHO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 118228-17-4
trans-Re(CO)4(PPh₃)2BF₄

: tetraethylammonium borohydride

: 118228-22-1
mer,trans-Re(CO)3(PPh₃)2CHO

Guidance literature:: In methanol; addn. of Et4NBH4 to stirred slurry of Re(CO)4(PPh)2.BF4 under N2 at room temp. and stirring continued till ceasing of gas evolution (5-10 mins.), pptn.; filtration under N2, washing with methanol, drying in vacuo;

Reference yield: 1.0%

: 146283-26-3
[HPt(1,2-bis(dimethylphosphino)ethane)₂][PF₆]

: 118228-17-4,1193374-25-2
[Re(CO)4(P(C₆H₅)3)2]⁽¹⁺⁾*BF₄^(1-)=[Re(CO)4(P(C₆H₅)3)2][BF₄]

: 25838-69-1,64626-67-1,82443-74-1
[Re(P(C₆H₅)3)(CO)4(H)]

: 25734-54-7
[Re(P(C₆H₅)3)2(CO)3(H)]

: 118228-22-1
[Re(CO)3(P(C₆H₅)3)2(CHO)]

Guidance literature:: In further solvent(s); suspn. of Re complex and Pt complex in C6D5Cl was kept for 48 h;
DOI:10.1021/om100638d

Reference yield: 96.0%

: 118228-22-1
mer,trans-Re(CO)3(PPh₃)2CHO

: 333-27-7
methyl trifluoromethanesulfonate

: mer,trans-{Re(CO)3(PPh₃)2(CH(OMe))}(CF₃SO₃)

Guidance literature:: In dichloromethane; N2 atmosphere; addn. of Re-complex to CH3SO3CF3 in CH2Cl2 (slow, 0°C, stirring, 2 min); pentane addn., crystn. on cooling (-20°C, several hours), filtration off, washing (pentane), drying (vac.); elem. anal.;
DOI:10.1021/om00156a038