(R)-cyclohexyl methyl sulfoxide

Base Information

• Chemical Name: (R)-cyclohexyl methyl sulfoxide
• CAS No.: 93183-66-5
• Molecular Formula: C₇H₁₄OS
• Molecular Weight: 146.254
• Mol file: 93183-66-5.mol

Synonyms:(R)-cyclohexyl methyl sulfoxide

Chemical Property of (R)-cyclohexyl methyl sulfoxide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (R)-cyclohexyl methyl sulfoxide

There total 8 articles about (R)-cyclohexyl methyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

cyclohexyl methyl sulfide (7133-37-1) → (R)-cyclohexyl methyl sulfoxide (93183-66-5)

Guidance literature:

With C₈₈H₉₀N₂O₆P₂; dihydrogen peroxide; magnesium sulfate; In cyclohexane; water; at 0 ℃; for 2h; optical yield given as %ee; enantioselective reaction;

DOI:10.1021/ja3035637

Reference yield:

cyclohexyl methyl sulfide (7133-37-1) → (S)-(+)-cyclohexyl methyl sulfoxide + (R)-cyclohexyl methyl sulfoxide (93183-66-5)

Guidance literature:

With <(3,3-dimethoxycamphoryl)sulfonyl>imine; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1016/0957-4166(95)00384-3

Reference yield:

cyclohexyl methyl sulfide (7133-37-1) → (methylsulfonyl)cyclohexane (60260-74-4) + (S)-(+)-cyclohexyl methyl sulfoxide + (R)-cyclohexyl methyl sulfoxide (93183-66-5)

Guidance literature:

With dihydrogen peroxide; chiral Fe(III) salan complex; at 20 ℃; for 3h; Title compound not separated from byproducts.;

DOI:10.1021/ja071916+

upstream raw materials:

cyclohexyl methyl sulfide

1,2:5,6-di-O-isopropylidene-α-D-glucofuranosyl (S)-cyclohexanesulfinate

methyl iodide

Cyclohexanesulfinyl chloride