(+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

Base Information

Chemical Name:(+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane
CAS No.:1353547-45-1
Molecular Formula:C₂₉H₄₈O₂S₂Si₂
Molecular Weight:549.002
Hs Code.:

Synonyms:(+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

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Chemical Property of (+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

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Technology Process of (+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

There total 3 articles about (+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1353547-44-0
(+)-(R)-2-(bis(phenylthio)methyl)butane-1,4-diol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1353547-45-1
(+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: With 1H-imidazole; In dichloromethane; at 20 ℃;
DOI:10.1039/c1ob06700a

Reference yield:

: 1353547-43-9
(-)-(4R,5R)-4-(bis(phenylthio)methyl)-5-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyloxy)dihydrofuran-2(3H)-one

: 1353547-45-1
(+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 0 °C

1.2: 20 °C

2.1: 1H-imidazole / dichloromethane / 20 °C

With 1H-imidazole; lithium aluminium tetrahydride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1039/c1ob06700a

Reference yield:

: 3561-67-9
bis(phenylthio)methane

: 1353547-45-1
(+)-(R)-6-(bis(phenylthio)methyl)-2,2,3,3,10,10,11,11-octamethyl-4,9-dioxa-3,10-disiladodecane

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C

2.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 0 °C

2.2: 20 °C

3.1: 1H-imidazole / dichloromethane / 20 °C

With 1H-imidazole; lithium aluminium tetrahydride; n-butyllithium; In tetrahydrofuran; diethyl ether; dichloromethane; 1.2: Michael condensation;
DOI:10.1039/c1ob06700a