1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

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Chemical Name:1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol
CAS No.:152868-70-7
Molecular Formula:C₇₀H₉₆NO₁₁P
Molecular Weight:1158.51
Hs Code.:

1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

Synonyms:1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

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Chemical Property of 1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

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Technology Process of 1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

There total 11 articles about 1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 87357-67-3
(R)-3-benzyloxytetradecanoic acid

: 1D-(1,2,4/3,5)-4,7-O-benzylidene-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

: 152868-70-7
1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; for 24h; Ambient temperature;
DOI:10.1016/S0040-4020(01)88023-6

Reference yield:

: 121788-68-9
(3aR,4R,5R,6R,7aS)-4,5-dihydroxy-6-(hydroxymethyl)hexahydrobenzo[d]oxazol-2(3H)-one

: 152868-70-7
1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

Guidance literature:: Multi-step reaction with 10 steps

1: 54 percent / PTSA / dimethylformamide / 3 h / 60 °C / 18 Torr

2: 71 percent / NaH / dimethylformamide / 2 h / 20 °C

3: 95 percent / acetic acid; H₂O / 24 h / Ambient temperature

4: 93 percent / LiOH / methanol; H₂O / 90 °C

5: 78 percent / dimethylformamide / Ambient temperature

6: 86 percent / ZnCl₂ / 0.5 h / Ambient temperature

7: tetrazole / acetonitrile / 0.5 h / Ambient temperature

8: t-BuOOH / CH₂Cl₂; acetonitrile / 2 h

9: 62 percent / SeO₂ / acetic acid; dioxane / 2 h / 100 °C

10: 52 percent / 4-dimethylaminopyridine (DMAP), dicyclohexylcarbodiimide (DCC) / CH₂Cl₂ / 24 h / Ambient temperature

With 1H-tetrazole; tert.-butylhydroperoxide; dmap; lithium hydroxide; selenium(IV) oxide; sodium hydride; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; zinc(II) chloride; In 1,4-dioxane; methanol; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4020(01)88023-6

Reference yield:

: 106265-22-9
(1S,2S,3R,4R,5R)-3,4-di-O-benzyl-2-benzylamino-1,2-N,O-carbonyl-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

: 152868-70-7
1D-(1,2,4/3,5)-4,7-O-benzylidene-3-O-<(R)-3-benzyloxytetradecanoyl>-2-<(R)-3-benzyloxytetradecanoylamido>-1-O-dibenzylphosphono-5-C-hydroxymethyl-1,3,4-cyclohexanetriol

Guidance literature:: Multi-step reaction with 11 steps

1: Li/NH₃(l) / tetrahydrofuran / 0.5 h / -78 °C

2: 54 percent / PTSA / dimethylformamide / 3 h / 60 °C / 18 Torr

3: 71 percent / NaH / dimethylformamide / 2 h / 20 °C

4: 95 percent / acetic acid; H₂O / 24 h / Ambient temperature

5: 93 percent / LiOH / methanol; H₂O / 90 °C

6: 78 percent / dimethylformamide / Ambient temperature

7: 86 percent / ZnCl₂ / 0.5 h / Ambient temperature

8: tetrazole / acetonitrile / 0.5 h / Ambient temperature

9: t-BuOOH / CH₂Cl₂; acetonitrile / 2 h

10: 62 percent / SeO₂ / acetic acid; dioxane / 2 h / 100 °C

11: 52 percent / 4-dimethylaminopyridine (DMAP), dicyclohexylcarbodiimide (DCC) / CH₂Cl₂ / 24 h / Ambient temperature

With 1H-tetrazole; tert.-butylhydroperoxide; dmap; lithium hydroxide; selenium(IV) oxide; ammonia; lithium; sodium hydride; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; zinc(II) chloride; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4020(01)88023-6