methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside

Base Information

Chemical Name:methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside
CAS No.:121843-57-0
Molecular Formula:C₂₆H₃₁NO₈
Molecular Weight:485.534
Hs Code.:

Synonyms:methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside

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Chemical Property of methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside

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Technology Process of methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside

There total 1 articles about methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 121843-56-9
methyl-4,6-O-benzylidene-muramic acid

: 100-39-0
benzyl bromide

: 121843-57-0
methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; Ambient temperature;
DOI:10.1016/S0040-4020(01)97594-5

Reference yield: 73.0%

: 121843-57-0
methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside

: 121843-58-1
methyl 2-acetamido-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside

Guidance literature:: With acetic acid; for 1h; Heating;
DOI:10.1016/S0040-4020(01)97594-5

Reference yield:

: 121843-57-0
methyl 2-acetamido-4,6-O-benzylidene-3-O-<(R)-1'-benzylcarboxyethyl>-2-deoxy-α,β-D-glucopyranoside

: 121788-66-7
1D-(1,2,4/3,5)-2-acetamido-1,4,5-tri-O-acetyl-3-O-<(R)-1'-carboxyethyl>-1,3,4,5-cyclohexanetetrol

Guidance literature:: Multi-step reaction with 9 steps

1: 73 percent / aq. acetic acid / 1 h / Heating

2: pyridine / Ambient temperature

3: 4-dimethylaminopyridine / 18 h

4: 91 percent / KI / dimethylformamide / 1 h / 100 °C

5: 83 percent / AgF, pyridine / Ambient temperature

6: 52 percent / HgSO₄, aq. H₂SO₄ / dioxane / 2 h / 80 °C

7: lithium aluminium-tri-tert-butoxyhydride / tetrahydrofuran / 0.67 h / 0 °C

8: Et₃N, 4-dimethylaminopyridine / CH₂Cl₂ / Ambient temperature

9: H₂ / Pd/C (10percent) / ethanol / 2 h / 1500.1 Torr

With pyridine; dmap; sulfuric acid; hydrogen; silver fluoride; mercury(II) sulfate; acetic acid; lithium tri-t-butoxyaluminum hydride; triethylamine; potassium iodide; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)97594-5