Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester

Base Information

Chemical Name:Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester
CAS No.:908297-98-3
Molecular Formula:C₁₇H₂₈O₄
Molecular Weight:296.407
Hs Code.:

Synonyms:Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester

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Chemical Property of Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester

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Technology Process of Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester

There total 8 articles about Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 908297-93-8
(6R,7S,9R)-7-hydroxy-γ-dihydroionol

: 108-24-7
acetic anhydride

: 908297-95-0
(-)-(6R,7S,9R)-7-hydroxy-γ-dihydroionol acetate

: 908297-98-3
Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester

Guidance literature:: With pyridine; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1016/j.tetasy.2006.05.024

Reference yield:

: (6RS,7SR)-7-hydroxy-α-dihydroionone

: 908297-98-3
Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 87 percent / tetramethylammonium triacetoxyborohydride; acetic acid / acetonitrile / 15 h / -10 °C

2: pyridine / 24 h / 20 °C

3: propan-2-ol; xylene / 144 h / Irradiation

4: 0.9 g / KOH / methanol / 20 °C

5: 43 percent / Pseudomonas cepacia lipase PS / various solvent(s) / 96 h / 20 °C

6: 5 percent / pyridine / CH₂Cl₂ / 24 h / 20 °C

With pyridine; potassium hydroxide; Pseudomonas cepacia lipase PS; acetic acid; tetramethylammonium triacetoxyborohydride; In methanol; dichloromethane; isopropyl alcohol; acetonitrile; xylene;
DOI:10.1016/j.tetasy.2006.05.024

Reference yield:

: (6RS,7SR,9RS)-7-hydroxy-α-dihydroionol

: 908297-98-3
Acetic acid (1S,3R)-3-acetoxy-1-((R)-2,2-dimethyl-6-methylene-cyclohexyl)-butyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: pyridine / 24 h / 20 °C

2: propan-2-ol; xylene / 144 h / Irradiation

3: 0.9 g / KOH / methanol / 20 °C

4: 43 percent / Pseudomonas cepacia lipase PS / various solvent(s) / 96 h / 20 °C

5: 5 percent / pyridine / CH₂Cl₂ / 24 h / 20 °C

With pyridine; potassium hydroxide; Pseudomonas cepacia lipase PS; In methanol; dichloromethane; isopropyl alcohol; xylene;
DOI:10.1016/j.tetasy.2006.05.024