Technology Process of C45H54O6
There total 1 articles about C45H54O6 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
1-tetradecene;
With
9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 6h;
C31H25IO6;
With
tetrakis(triphenylphosphine) palladium(0); potassium carbonate;
In
tetrahydrofuran; N,N-dimethyl-formamide;
at 50 ℃;
for 16h;
DOI:10.1021/jo3011683
- Guidance literature:
-
With
water; potassium hydroxide;
In
ethanol;
for 16h;
Reflux;
DOI:10.1021/jo3011683
- Guidance literature:
-
Multi-step reaction with 5 steps
1: potassium hydroxide; water / ethanol / 16 h / Reflux
2: oxalyl dichloride; N,N-dimethyl-formamide / tetrahydrofuran; dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere
3: sodium azide / acetone; water / 1 h / 0 °C
4: benzyl alcohol / toluene / 2 h / Reflux; Inert atmosphere
5: potassium hydroxide / ethanol; water / 18 h / 95 °C
With
sodium azide; oxalyl dichloride; water; N,N-dimethyl-formamide; potassium hydroxide; benzyl alcohol;
In
tetrahydrofuran; ethanol; dichloromethane; water; acetone; toluene;
4: |Curtius Rearrangement;
DOI:10.1021/jo3011683