(2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol

Base Information

Chemical Name:(2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol
CAS No.:108330-82-1
Molecular Formula:C₂₇H₄₁F₇O₄
Molecular Weight:562.609
Hs Code.:

Synonyms:(2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol

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Chemical Property of (2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol

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Technology Process of (2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol

There total 9 articles about (2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 108330-79-6
(R)-4-[(R)-1-Benzyloxy-2-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-ethyl]-2,2-dimethyl-[1,3]dioxolane

: 108330-82-1
(2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; for 2h; Ambient temperature;
DOI:10.1248/cpb.35.647

Reference yield:

: 50816-18-7
9-decen-1-yl acetate

: 108330-82-1
(2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol

Guidance literature:: Multi-step reaction with 9 steps

1: Fe₃(CO)12 / 5.5 h / 80 °C

2: Zn powder / acetic acid; diethyl ether / 1 h / Ambient temperature

3: 5 percent methanolic KOH / 2 h / Ambient temperature

4: 85 percent / triphenylphosphine dibromide / dimethylformamide; acetonitrile

5: 40 percent / 0.1 M Li₂CuCl₄ / tetrahydrofuran / 5 h / Ambient temperature

6: 80 percent / H₂ / 5 percent Pd-C / ethanol; acetic acid / Ambient temperature

7: 87 percent / pyridine / 1 h / Ambient temperature

8: 75 percent / 22 percent KH / benzene; paraffin / 1.) 30 min; 2.) 10 h, RT

9: 77 percent / 2 N HCl / tetrahydrofuran / 2 h / Ambient temperature

With hydrogenchloride; potassium hydroxide; hydrogen; potassium hydride; zinc; dibromotriphenylphosphorane; palladium on activated charcoal; dilithium tetrachlorocuprate; triiron dodecarbonyl; In tetrahydrofuran; pyridine; diethyl ether; ethanol; acetic acid; N,N-dimethyl-formamide; acetonitrile; paraffin; benzene;
DOI:10.1248/cpb.35.647

Reference yield:

: 102197-76-2
1-bromo-11,11,12,12,13,13,13-heptafluorotridecane

: 108330-82-1
(2R,3R)-3-Benzyloxy-4-(14,14,15,15,16,16,16-heptafluoro-hexadecyloxy)-butane-1,2-diol

Guidance literature:: Multi-step reaction with 5 steps

1: 40 percent / 0.1 M Li₂CuCl₄ / tetrahydrofuran / 5 h / Ambient temperature

2: 80 percent / H₂ / 5 percent Pd-C / ethanol; acetic acid / Ambient temperature

3: 87 percent / pyridine / 1 h / Ambient temperature

4: 75 percent / 22 percent KH / benzene; paraffin / 1.) 30 min; 2.) 10 h, RT

5: 77 percent / 2 N HCl / tetrahydrofuran / 2 h / Ambient temperature

With hydrogenchloride; hydrogen; potassium hydride; palladium on activated charcoal; dilithium tetrachlorocuprate; In tetrahydrofuran; pyridine; ethanol; acetic acid; paraffin; benzene;
DOI:10.1248/cpb.35.647