bromo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I)

Base Information

• Chemical Name: bromo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I)
• CAS No.: 253875-01-3
• Molecular Formula: C₃₄H₃₃BrP₃Rh
• Molecular Weight: 717.367
• Mol file: 253875-01-3.mol

Synonyms:bromo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I)

Chemical Property of bromo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I)

Chemical Property:

Purity/Quality:

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Technology Process of bromo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I)

There total 1 articles about bromo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.4%

η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate (214194-22-6) + potassium bromide (7558-02-3,7758-02-3) → bromo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) (253875-01-3)

Guidance literature:

With 18-crown-6; In toluene; Ar-atmosphere; 80°C (72 h); decanting, concg. (vac.), pptn. on H2O addn., filtering, washing (H2O, hexane), drying (vac., room temp., 20 h, 60°C, 48 h); elem. anal.;

DOI:10.1021/om9905106

upstream raw materials:

η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate

potassium bromide