η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate

Base Information

Chemical Name:η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate
CAS No.:214194-22-6
Molecular Formula:C₄₁H₄₁P₃Rh*F₆Sb
Molecular Weight:965.344
Hs Code.:

Synonyms:η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate

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Chemical Property of η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate

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Technology Process of η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate

There total 1 articles about η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.1%

: 16925-25-0
sodium hexafluoroantimonate

: 12257-42-0
[(norbornadiene)rhodium(I)chloride]2

: 23582-02-7
bis(2-diphenylphosphinoethyl)phenylphosphine

: 214194-22-6
η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate

Guidance literature:: In tetrahydrofuran; acetone; N2 or Ar-atmosphere; stirring (room temp., 4 h), evapn. (vac.), Me2CO and NaSbF6 soln. (Me2CO) addn.; evapn. (vac., room temp.), CH2Cl2 addn., filtering, washing (CH2Cl2), evapn., chromy. (SiO2, C6H6, CH2Cl2), evapn., drying (vac., overnight); elem. anal.x;
DOI:10.1021/om9905106

Reference yield: 71.4%

: 214194-22-6
η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate

: 7558-02-3,7758-02-3
potassium bromide

: 253875-01-3
bromo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I)

Guidance literature:: With 18-crown-6; In toluene; Ar-atmosphere; 80°C (72 h); decanting, concg. (vac.), pptn. on H2O addn., filtering, washing (H2O, hexane), drying (vac., room temp., 20 h, 60°C, 48 h); elem. anal.;
DOI:10.1021/om9905106

Reference yield: 69.5%

: 214194-22-6
η(4)-(bicyclo[2.2.1]hepta-2,5-diene)-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I) hexafluoroantimonate

: 7681-11-0
potassium iodide

: 253875-02-4
iodo-η(3)-(bis(diphenylphosphinoethyl)phenylphosphine)rhodium(I)

Guidance literature:: With 18-crown-6; In toluene; Ar-atmosphere; 80°C (1 h); decanting, concg. (vac.), pptn. on H2O addn., filtering, washing (H2O, hexane), drying (vac., room temp., 20 h, 60°C, 48 h); elem. anal.;
DOI:10.1021/om9905106