tatanan A

Base Information

• Chemical Name: tatanan A
• CAS No.: 1280155-75-0
• Molecular Formula: C₃₆H₄₈O₉
• Molecular Weight: 624.772
• Mol file: 1280155-75-0.mol

Synonyms:tatanan A

Chemical Property of tatanan A

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tatanan A

There total 8 articles about tatanan A which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

5,5'-((3R,4S,5R,E)-1-iodo-2,4-dimethylhept-1-ene-3,5-diyl)bis(1,2,4-trimethoxybenzene) + (2,4,5-trimethoxyphenyl)boronic acid (213698-56-7) → tatanan A (1280155-75-0)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; silver(l) oxide; In tetrahydrofuran; water; at 20 ℃; stereoselective reaction; Sealed tube; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201609598

Reference yield:

1-iodo-2,4,5-trimethoxybenzene (23149-33-9) → tatanan A (1280155-75-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere; Schlenk technique

1.2: 20 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; silver(l) oxide / tetrahydrofuran; water / 20 °C / Sealed tube; Inert atmosphere; Schlenk technique

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; silver(l) oxide; In tetrahydrofuran; hexane; water;

DOI:10.1002/anie.201609598

Reference yield:

1,2,4-trimethoxy-benzene (135-77-3) → tatanan A (1280155-75-0)

Guidance literature:

Multi-step reaction with 3 steps

1.1: N-iodo-succinimide / acetonitrile / 16 h / 20 °C / Inert atmosphere; Schlenk technique

2.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere; Schlenk technique

2.2: 20 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; silver(l) oxide / tetrahydrofuran; water / 20 °C / Sealed tube; Inert atmosphere; Schlenk technique

With N-iodo-succinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; silver(l) oxide; In tetrahydrofuran; hexane; water; acetonitrile;

DOI:10.1002/anie.201609598

upstream raw materials:

1-iodo-2,4,5-trimethoxybenzene

1,2,4-trimethoxy-benzene

(2,4,5-trimethoxyphenyl)boronic acid