3,9,10-TRIBROMO-(+)-CAMPHOR

Base Information

• Chemical Name: 3,9,10-TRIBROMO-(+)-CAMPHOR
• CAS No.: 85706-52-1
• Molecular Formula: C₁₀H₁₃Br₃O
• Molecular Weight: 388.925
• Hs Code.: 2914700090
• Mol file: 85706-52-1.mol

Synonyms:Bicyclo[2.2.1]heptan-2-one,3-bromo-1,7-bis(bromomethyl)-7-methyl-, [1S-(endo,anti)]-;(+)-3,9,10-Tribromocamphor; 3,9,10-Tribromocamphor

Chemical Property of 3,9,10-TRIBROMO-(+)-CAMPHOR

Chemical Property:

• Vapor Pressure: 5.36E-06mmHg at 25°C
• Refractive Index: 1.599
• Boiling Point: 380.7°C at 760 mmHg
• Flash Point: 111.5°C
• PSA: 17.07000
• Density: 1.966g/cm³
• LogP: 3.52510

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,9,10-TRIBROMO-(+)-CAMPHOR

There total 5 articles about 3,9,10-TRIBROMO-(+)-CAMPHOR which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

3-endo-9-dibromo-1,7,7-trimethylbicyclo<2.2.1>heptan-2-one (10293-10-4) → (+)-endo-3,9,10-tribromocamphor (85706-52-1)

Guidance literature:

With chlorosulfonic acid; bromine; In chloroform; for 120h; Ambient temperature;

Reference yield:

(1R)-3-endo-bromocamphor (10293-06-8) → (+)-endo-3,9,10-tribromocamphor (85706-52-1)

Guidance literature:

Multi-step reaction with 2 steps

1: Br₂, ClSO₃H / 5 h

2: 50 percent / Br₂, ClSO₃H / CHCl₃ / 120 h / Ambient temperature

With chlorosulfonic acid; bromine; In chloroform;

Reference yield:

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one (464-49-3,68546-28-1) → (+)-endo-3,9,10-tribromocamphor (85706-52-1)

Guidance literature:

Multi-step reaction with 3 steps

1: Br₂, HOAc

2: Br₂, ClSO₃H / 5 h

3: 50 percent / Br₂, ClSO₃H / CHCl₃ / 120 h / Ambient temperature

With chlorosulfonic acid; bromine; acetic acid; In chloroform;

upstream raw materials:

3-endo-9-dibromo-1,7,7-trimethylbicyclo<2.2.1>heptan-2-one

(1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

(1R)-3-endo-bromocamphor

(+)-endo-3,9-dibromocamphor

Downstream raw materials:

(+)-endo-9,10-dibromocamphor

(1S)-9,10-dibromocamphor

(1R,4R,7R)-9-bromocamphor

(-)-anti-7,9-dibromofenchone