η5-indenyldicarbonyltriphenylphosphinerhenium

Base Information

Chemical Name:η5-indenyldicarbonyltriphenylphosphinerhenium
CAS No.:78670-96-9
Molecular Formula:C₂₉H₂₂O₂PRe
Molecular Weight:619.673
Hs Code.:

Synonyms:η5-indenyldicarbonyltriphenylphosphinerhenium

Suppliers and Price of η5-indenyldicarbonyltriphenylphosphinerhenium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of η5-indenyldicarbonyltriphenylphosphinerhenium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of η5-indenyldicarbonyltriphenylphosphinerhenium

There total 2 articles about η5-indenyldicarbonyltriphenylphosphinerhenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: indenyl(tricarbonyl)rhenium

: 78670-96-9
η5-indenyldicarbonyltriphenylphosphinerhenium

Guidance literature:: With triphenylphosphine; In toluene; under inert atmosphere, soln. boiled for 18 h; solvent removed in vac., residue chromd. (Al2O3), eluted (petroleum ether/CHCl3), chromd. (Al2O3); elem. anal.;
DOI:10.1007/BF00955267

Reference yield:

: 186799-67-7
dicarbonyl(η2-2-butyne)(η5-indenyl)rhenium

: 1641-69-6
[13C]Carbon monoxide

: 603-35-0
triphenylphosphine

: 78670-96-9
η5-indenyldicarbonyltriphenylphosphinerhenium

: 505066-50-2
(η5-indenyl)Re((13)CO)(CO)2

: 505066-51-3
(η5-indenyl)Re((13)CO)2(CO)

: 505066-53-5
(η5.indenyl)Re((13)CO)3

: 505066-55-7
(η5-indenyl)Re((13)CO)(CO)(PPh3)

Guidance literature:: In not given; byproducts: (η5-C9H7)Re((13)CO)2(P(C6H5)3); High Pressure; at 25°C, 4 atm (13)CO, in the presence of PPh3 (0.42 M); TLC, amount of (13)CO incorporation detected by MS; Kinetics;
DOI:10.1021/om020884q

Reference yield: 7.0%

: nitronium tetrafluoborate

: 78670-96-9
η5-indenyldicarbonyltriphenylphosphinerhenium

: {(η5-indenyl)carbonyl(nitrosyl)(PPh3)rhenium}(BF4)

Guidance literature:: In nitromethane; dichloromethane; under inert atmosphere, NO2BF4 added with stirring (-15°C) to soln. of C9H7Re(CO)2PPh3, mixed for 1 h at 20°C; evapd., washed twice (ether), recrystd. (C2H5OH, CH2Cl2/hexane);
DOI:10.1007/BF00955267