Ru(CO₃)(CO)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine)

Base Information

• Chemical Name: Ru(CO₃)(CO)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine)
• CAS No.: 84623-58-5
• Molecular Formula: C₃₈H₆₁O₄P₃Ru
• Molecular Weight: 775.891
• Mol file: 84623-58-5.mol

Synonyms:Ru(CO₃)(CO)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine)

Chemical Property of Ru(CO₃)(CO)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(CO₃)(CO)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine)

There total 4 articles about Ru(CO₃)(CO)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

ruthenium(dicarbonyl)(Cyttp) (83146-93-4) → Ru(CO3)(CO)(bis(3-(dicyclohexylphosphino)propyl)phenylphosphine) (84623-58-5)

Guidance literature:

With air; In neat (no solvent, solid phase); complex exposed to air for 1 wk; washed with C6H6 in air, then with Et2O, dried (air); elem. anal.;

DOI:10.1021/om00078a001

Reference yield: 95.0%

[cis-mer-Ru((BF4)2(CO)(PhP(CH2CH2CH2P(cyclohexyl)2)2)] + sodium carbonate (497-19-8) → [mer-anti-Ru(II)(κ2-carbonato)(CO)(PhP(CH2CH2CH2P(cyclohexyl)2)2)] (850554-60-8,84623-58-5,850554-57-3)

Guidance literature:

In water; acetone; mixt. of Ru-complex and Na2CO3 dissolved in acetone/H2O; stirred for 30 min; vol. of soln. reduced; ppt. collected on a filter frit, washed twice (H2O, hexane), dried undervac. overnight; elem. anal.;

DOI:10.1016/j.molcata.2004.07.029

Reference yield: 86.0%

ruthenium(dicarbonyl)(Cyttp) (83146-93-4) + oxygen (80937-33-3) → [mer-anti-Ru(II)(κ2-carbonato)(CO)(PhP(CH2CH2CH2P(cyclohexyl)2)2)] (850554-60-8,84623-58-5,850554-57-3) + [mer-syn-Ru(II)(κ2-carbonato)(CO)(PhP(CH2CH2CH2P(cyclohexyl)2)2)] (84623-58-5,850554-57-3,850554-60-8)

Guidance literature:

In neat (no solvent, solid phase); powdery Ru-complex exposed to a stream of O2 for 10 d; solid wetted (Et2O), collected on a filter frit, washed (benzene), rinzed (Et2O), dried under vac.;

DOI:10.1016/j.molcata.2004.07.029

upstream raw materials:

sodium carbonate

ruthenium(dicarbonyl)(Cyttp)

oxygen

Downstream raw materials:

[cis-mer-anti-Ru(II)Cl₂(CO)(PhP(CH₂CH₂CH₂P(cyclohexyl)2)2)]

[mer-anti-Ru(II)(κ2-O2COEt)(CO)(PhP(CH2CH2CH2P(cyclohexyl)2)2)]PF6

[mer-anti-Ru(II)(κ2-O2COMe)(CO)(PhP(CH2CH2CH2P(cyclohexyl)2)2)]BF4

[cis-mer-anti-Ru(II)I₂(CO)(PhP(CH₂CH₂CH₂P(cyclohexyl)2)2)]