Sodium Carbonate

Base Information

• Chemical Name: Sodium Carbonate
• CAS No.: 497-19-8
• Deprecated CAS: 1332-57-6,1314087-39-2,1977561-09-3,1314087-39-2
• Molecular Formula: Na2CO3
• Molecular Weight: 105.989
• Hs Code.: 28362000
• European Community (EC) Number: 207-838-8,231-420-4
• ICSC Number: 1135
• UNII: 45P3261C7T
• DSSTox Substance ID: DTXSID1029621
• Nikkaji Number: J405G
• Wikipedia: Sodium carbonate,Sodium_carbonate
• Wikidata: Q190227
• NCI Thesaurus Code: C47721
• RXCUI: 36685
• ChEMBL ID: CHEMBL186314
• Mol file: 497-19-8.mol

Synonyms:disodium carbonate, 14C-labeled cpd;disodium carbonate, heptahydrate;disodium carbonate, monohydrate;monosodium carbonate, 14C-labeled cpd;monosodium carbonate, monohydrate;sodium carbonate;sodium carbonate (2:3), dihydrate;sodium carbonate (4:5);sodium carbonate decahydrate;sodium carbonate, hydrate

Chemical Property of Sodium Carbonate

Chemical Property:

• Appearance/Colour: white odourless powder
• Melting Point: 851 °C
• Refractive Index: 1.535
• Boiling Point: 333.6 °C at 760 mmHg
• PKA: (1) 6.37, (2) 10.25 (carbonic (at 25℃)
• Flash Point: 169.8 °C
• PSA: 63.19000
• Density: 2.54 g/cm³
• LogP: -2.44700
• Storage Temp.: 2-8°C
• Sensitive.: Hygroscopic
• Solubility.: H2O: 1 M at 20 °C, clear, colorless
• Water Solubility.: 22 g/100 mL (20 ºC)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 105.96428242
• Heavy Atom Count: 6
• Complexity: 18.8

Purity/Quality:

≥99.2% ^*data from raw suppliers

Sodium carbonate anhydrous ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, Xi
• Hazard Codes: Xn,Xi
• Statements: 32-36-51/53-36/37/38-41-37/38
• Safety Statements: 36/37-26-22-36-39

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metals, Inorganic Compounds
• Canonical SMILES: C(=O)([O-])[O-].[Na+].[Na+]
• Inhalation Risk: A harmful concentration of airborne particles can be reached quickly , especially if powdered.
• Effects of Short Term Exposure: The substance is irritating to the eyes, skin and respiratory tract.
• Effects of Long Term Exposure: The substance may have effects on the respiratory tract. This may result in perforation of the nasal septum. Repeated or prolonged contact with skin may cause dermatitis.
• Chemical Properties and Applications in Cement Setting: Sodium carbonate is an organic sodium salt and a carbonate salt.; It is the disodium salt of carbonic acid with alkalinizing property.; Sodium carbonate, along with sodium phosphate, is commonly used for controlling cement setting and hardening.; It forms carbonic acid and sodium hydroxide when dissolved in water.; Sodium carbonate and sodium phosphate immediately precipitate in the presence of calcium ions, depositing on the surface of cement as one layer in cement paste.; Sodium carbonate accelerates cement hydration due to the interspace in the calcium carbonate-based layer facilitating ion dissolution.
• Applications in Cement Production: Sodium carbonate is used as an alternative to strong base activators in the preparation of one-part alkali-activated slag (AAS) cements.; It promotes cast-in-situ applications by simplifying the preparation process, leading to cost savings and reduced health and safety risks for handlers.; Na2CO3 can efficiently activate ground granulated blast furnace slag, resulting in compressive strengths of around 30鈥?40 MPa after 28 days of curing at ambient temperature.
• Applications in Food Preservation: Sodium carbonate has been shown to decrease the development of green mold (Penicillium digitatum) on lemons without negatively affecting their organoleptic characteristics.; Organic acids such as ascorbic, acetic, oxalic, tartaric, and lactic acid are commonly used in the food industry for their antimicrobial ability by lowering the pH inside and outside of microorganisms.
• Applications in Composite Materials: Sodium carbonate has been used as a treatment for natural coir fibers, enhancing composite properties such as tensile strength.; It removes amorphous compounds from fibers, improving composite properties, although it may reduce impact strength due to less fiber pull-out.; Sodium carbonate is compared to sodium hydroxide in terms of modifying fiber surfaces, with advantages including less degradation behavior towards fibers and eco-friendly nature, as well as shorter treatment times compared to sodium bicarbonate.

Technology Process of Sodium Carbonate

There total 392 articles about Sodium Carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Na2[B(CN)3] + water (7732-18-5) + potassium carbonate (584-08-7) → K[HB(CN)3] + sodium carbonate (497-19-8) + sodium hydroxide (1310-73-2)

Guidance literature:

With tetrahydrofuran;

Reference yield: 97.0%

carbon monoxide (201230-82-2) + water (7732-18-5) + sodium sulfate (7757-82-6) → sodium carbonate (497-19-8)

Guidance literature:

iron(III) oxide; In neat (no solvent); passing a mixture of CO/H2O-vapor over powdered Na2SO4 at 660°C; partial pressure of H2O: 0.3 at, catalyst: Fe2O3 in form of a Fe(NO3)2-soln.;; 85-92% Na2CO3;;

Reference yield: 94.0%

disodium tetracarbonylferrate + carbon dioxide (124-38-9,18923-20-1) → iron pentacarbonyl (13463-40-6,37220-42-1) + sodium carbonate (497-19-8)

Guidance literature:

In tetrahydrofuran; reductive disproportionation, mechanism discussed;; IR; iron carbonyl not isolated;;

DOI:10.1021/ja00244a017

upstream raw materials:

ammonia

water

edetate disodium

alpha-D-glucopyranose

Downstream raw materials:

perixanthenoxanthene

naphthalene

5-methylisoxazole

2-Ethylhexyl alcohol

Refernces

• 1、 Seyrankaya, Abdullah,Ozalp, Bari?. "Dehydration of sodium carbonate monohydrate with indirect microwave heating". . p. 31 - 36. Retrieved 2006.
• 2、 Vlase,Vlase,Doca,Doca. "Specificity of decomposition of solids in non-isothermal conditions". . p. 597 - 604. Retrieved 2003.
• 3、 Heda, Pavan K.,Dollimore, David,Alexander, Kenneth S.,Chen, Dun,Law, Emmeline,Bicknell, Paul. "A method of assessing solid state reactivity illustrated by thermal decomposition experiments on sodium bicarbonate". . p. 255 - 272. Retrieved 1995.
• 4、 Awaleh,Ben Ali,Maisonneuve,Leblanc, Marc. "Microwave-assisted synthesis, crystal structures and thermal behaviour of Na5Y(CO3)4 and Na5Yb(CO3)4·2H2O". . p. 114 - 120. Retrieved 2003.
• 5、 Desjobert, Andre,Petek, Fahrettin. "-". . p. 19 - 23. Retrieved 1956.
• 6、 Krueger, A.. "". . p. 333 - 333. Retrieved 1939.
• 7、 Nagaishi, T.,Yoshimura, J.,Matsumoto, M.,Yoshinaga, S.. "". . p. 501 - 508. Retrieved 1980.
• 8、 Tananaeff, N. A.,Lasarkevitsch, N. A.. "-". . p. 117. Retrieved 1930.
• 9、 Suba,Udupa. "Solid state reaction between dichromates and oxalates". . p. 1197 - 1203. Retrieved 1989.
• 10、 Canossa, Stefano,Gonzalez-Nelson, Adrian,Shupletsov, Leonid,Van der Veen, Monique A.,del Carmen Martin, Maria. "Overcoming Crystallinity Limitations of Aluminium Metal-Organic Frameworks by Oxalic Acid Modulated Synthesis". . . Retrieved 2020.