methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside

Base Information

Chemical Name:methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside
CAS No.:96691-86-0
Molecular Formula:C₂₁H₂₅IO₇S
Molecular Weight:548.396
Hs Code.:

Synonyms:methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside

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Technology Process of methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside

There total 3 articles about methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 96691-85-9
methyl 3,4-anhydro-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-galactopyranoside

: 100-51-6,185532-71-2
benzyl alcohol

: 96691-86-0
methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at 18 ℃; for 120h;

Reference yield:

: 54497-89-1
methyl 2,6-bis-α-D-glucopyranoside

: 96691-86-0
methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: NaI / butan-2-one / 2 h / Heating

2: triphenylphosphine, di-isopropyl azodicarboxylate / toluene / 2 h / 90 °C

3: 61 percent / boron trifluoride-diethyl ether / CH₂Cl₂ / 120 h / 18 °C

With di-isopropyl azodicarboxylate; boron trifluoride diethyl etherate; triphenylphosphine; sodium iodide; In dichloromethane; toluene; butanone;

Reference yield:

: 96530-38-0
methyl 6-deoxy-6-iodo-2-O-p-toluenesulfonyl-α-D-glucopyranoside

: 96691-86-0
methyl 3-O-benzyl-6-deoxy-6-iodo-2-O-(p-tolylsulphonyl)-α-D-gulopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: triphenylphosphine, di-isopropyl azodicarboxylate / toluene / 2 h / 90 °C

2: 61 percent / boron trifluoride-diethyl ether / CH₂Cl₂ / 120 h / 18 °C

With di-isopropyl azodicarboxylate; boron trifluoride diethyl etherate; triphenylphosphine; In dichloromethane; toluene;