N-Lithio-N-(1-phenyl-1-propenyl)benzolamin

Base Information

• Chemical Name: N-Lithio-N-(1-phenyl-1-propenyl)benzolamin
• CAS No.: 127459-36-3
• Molecular Formula: C₁₅H₁₄N*Li
• Molecular Weight: 215.224
• Mol file: 127459-36-3.mol

Synonyms:N-Lithio-N-(1-phenyl-1-propenyl)benzolamin

Chemical Property of N-Lithio-N-(1-phenyl-1-propenyl)benzolamin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-Lithio-N-(1-phenyl-1-propenyl)benzolamin

There total 2 articles about N-Lithio-N-(1-phenyl-1-propenyl)benzolamin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

1,N-Diphenylpropanimine (14752-72-8) → N-Lithio-N-(1-phenyl-1-propenyl)benzolamin (127459-36-3)

Guidance literature:

With lithium diisopropyl amide; In diethyl ether; at -78 - 23 ℃; for 20h;

DOI:10.1021/acs.inorgchem.5b02990

Reference yield:

1-phenyl-propan-1-one (93-55-0) → N-Lithio-N-(1-phenyl-1-propenyl)benzolamin (127459-36-3)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene-4-sulfonic acid / toluene / 68 h / 23 °C / Molecular sieve

2: lithium diisopropyl amide / diethyl ether / 20 h / -78 - 23 °C

With toluene-4-sulfonic acid; lithium diisopropyl amide; In diethyl ether; toluene;

DOI:10.1021/acs.inorgchem.5b02990

Reference yield:

N-Lithio-N-(1-phenyl-1-propenyl)benzolamin (127459-36-3) → (Z)-N-Lithio-N-(1-phenyl-1-propenyl)benzolamin (74404-00-5,74404-05-0)

Guidance literature:

With propiophenone anil; In tetrahydrofuran; Yield given;

DOI:10.1021/ja00529a058

upstream raw materials:

1-phenyl-propan-1-one

1,N-Diphenylpropanimine

Downstream raw materials:

(E)-N-(1-Phenyl-1-propenyl)benzolamin

(Z)-N-(1-Phenyl-1-propenyl)benzolamin

(Z)-N-Lithio-N-(1-phenyl-1-propenyl)benzolamin