(C₂N₃(CH₂PPh₂)2)PtCl

Base Information

• Chemical Name: (C₂N₃(CH₂PPh₂)2)PtCl
• CAS No.: 1199247-75-0
• Molecular Formula: C₂₈H₂₄ClN₃P₂Pt
• Molecular Weight: 694.999
• Mol file: 1199247-75-0.mol

Synonyms:(C₂N₃(CH₂PPh₂)2)PtCl

Chemical Property of (C₂N₃(CH₂PPh₂)2)PtCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₂N₃(CH₂PPh₂)2)PtCl

There total 1 articles about (C₂N₃(CH₂PPh₂)2)PtCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + C2HN3(CH2PPh2)2 (1046818-15-8) → (C2N3(CH2PPh2)2)PtCl (1199247-75-0)

Guidance literature:

With Et₃N; In dimethylformamide; (N2); std. Schlenk technique; soln. of Pt complex in DMF and Et3N was added to soln. of ligand in DMF; sealed; heated to 70°C for 18 h; evapd. (vac.); washed (ether); extd. (toluene/THF); evapd.;

DOI:10.1021/om900827g

Reference yield: 73.0%

(C2N3(CH2PPh2)2)PtCl (1199247-75-0) + 4-bromomethyltrifluoromethylbenzene (402-49-3) → [(CF3C6H4CH2C2N3(CH2PPh2)2)PtCl]Br (1332340-56-3)

Guidance literature:

In acetonitrile; addn. of benzyl bromide deriv. to CH3CN soln. of platinum compd., heating at 70°C for 48 h; evapn., washing with hexane and toluene, extn. (THF), evapn., NMR and MS;

DOI:10.1039/c1dt10264h

Reference yield:

(C2N3(CH2PPh2)2)PtCl (1199247-75-0) → [(CF3C6H4CH2C2N3(CH2PPh2)2)PtCl](triflate) (1332340-61-0)

Guidance literature:

Multi-step reaction with 2 steps

1: acetonitrile

2: acetonitrile

In acetonitrile;

DOI:10.1039/c1dt10264h

upstream raw materials:

dichloro( 1,5-cyclooctadiene)platinum(ll)

C₂HN₃(CH₂PPh₂)2

Downstream raw materials:

[(CF₃C₆H₄CH₂C₂N₃(CH₂PPh₂)2)PtCl](triflate)

[(CF₃C₆H₄CH₂C₂N₃(CH₂PPh₂)2)PtCl]Br