(1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate

Base Information

Chemical Name:(1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate
CAS No.:1260152-97-3
Molecular Formula:C₂₈H₂₃N₃O₇
Molecular Weight:513.507
Hs Code.:

Synonyms:(1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate

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Technology Process of (1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate

There total 8 articles about (1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 1260152-95-1
(1R,2R,3S,6R)-6-(azidomethyl)cyclohex-4-ene-1,2,3-triyl tribenzoate

: 1260152-97-3
(1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate

: 1260152-96-2
8-azido-2,3,4-tri-O-benzoyl-8-deoxycyclophellitol

Guidance literature:: With Oxone; 1,1,1-trifluoro-2-propanone; edetate disodium; sodium hydrogencarbonate; In water; acetonitrile; at 0 - 4 ℃; for 4.5h; Inert atmosphere;
DOI:10.1002/ejoc.201402588

Reference yield: 20.0%

: 421-50-1
1,1,1-trifluoro-2-propanone

: 1260152-95-1
(1R,2R,3S,6R)-6-(azidomethyl)cyclohex-4-ene-1,2,3-triyl tribenzoate

: 1260152-97-3
(1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate

: 1260152-96-2
8-azido-2,3,4-tri-O-benzoyl-8-deoxycyclophellitol

Guidance literature:: With Oxone; edetate disodium; sodium hydrogencarbonate; In water; acetonitrile; at 4 ℃; for 4.5h;

Reference yield:

: 1260152-93-9
(1R,2R,5S,6S)-2-(azidomethyl)-5,6-bis(benzyloxy)cyclohex-3-enol

: 1260152-97-3
(1R,2S,3S,4R,5S,6R)-5-(azidomethyl)-7-oxabicyclo[4.1.0]heptan-2,3,4-triyl tribenzoate

: 1260152-96-2
8-azido-2,3,4-tri-O-benzoyl-8-deoxycyclophellitol

Guidance literature:: Multi-step reaction with 2 steps

1.1: boron trichloride / dichloromethane / 6 h / -78 °C

1.2: 18 h / 0 - 20 °C

2.1: sodium hydrogencarbonate; edetate disodium; Oxone / water; acetonitrile / 4.5 h / 4 °C

With Oxone; edetate disodium; boron trichloride; sodium hydrogencarbonate; In dichloromethane; water; acetonitrile;