(1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde

Base Information

Chemical Name:(1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde
CAS No.:97855-75-9
Molecular Formula:C₁₈H₂₈O₂
Molecular Weight:276.419
Hs Code.:

Synonyms:(1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde

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Chemical Property of (1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde

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Technology Process of (1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde

There total 20 articles about (1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 97855-74-8
6-[2-((1S,2S)-2-[1,3]Dioxolan-2-yl-2,6,6-trimethyl-cyclohexyl)-ethyl]-cyclohex-2-enone

: 97855-75-9
(1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde

Guidance literature:: With perchloric acid; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)98546-0

Reference yield:

: 97868-04-7
(2R,4aS,8aS)-(-)-1,2,3,4,4a,5,6,7,8,8a-decahydro-2α-hydroxy-5,5,8aβ-trimethyl-1-oxonaphthalene

: 97855-75-9
(1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 12 steps

1: lead tetra-acetate (LTA) / benzene / 0.17 h / Ambient temperature

2: NaBH₄ / methanol / 0.33 h / Ambient temperature

3: 98 percent / tributylphosphine / tetrahydrofuran / 0.33 h / Ambient temperature

4: 91 percent / hydrogen peroxide / tetrahydrofuran / 10 h / Ambient temperature

5: 1.) lithium aluminium hydride; 2.) sodium hydroxide / 1.) diethyl ether, rt, 30 min; 2.) water, 30 min.

6: 88 percent / Florisil, PCC / CH₂Cl₂ / 1 h / Ambient temperature

7: 98 percent / toluene-p-sulphonic acid / benzene / 0.33 h / Heating

8: 1. osmium tetraoxide; 2.) sodium periodate / 1.) diethyl ether, water, rt, 5 min; 2.) rt, 10 h.

9: 1.) lithium diisopropylamide (LDA) / 1.) THF, -78 deg C; 2.) THF, rt, 1 h.

10: 98 percent / H₂ / 10 percent palladium-charcoal / ethanol

12: 83 percent / 10 percent perchloric acid / tetrahydrofuran / 1 h / Ambient temperature

With lead(IV) acetate; sodium hydroxide; sodium tetrahydroborate; florisil; sodium periodate; osmium(VIII) oxide; lithium aluminium tetrahydride; perchloric acid; tributylphosphine; hydrogen; dihydrogen peroxide; toluene-4-sulfonic acid; pyridinium chlorochromate; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; methanol; ethanol; dichloromethane; benzene;

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 97855-75-9
(1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) lithium diisopropylamide (LDA) / 1.) THF, -78 deg C; 2.) THF, rt, 1 h.

2: 98 percent / H₂ / 10 percent palladium-charcoal / ethanol

4: 83 percent / 10 percent perchloric acid / tetrahydrofuran / 1 h / Ambient temperature

With perchloric acid; hydrogen; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; ethanol;