4'-(DIMETHYLAMINO)BENZYLIDENE-4-NITROANILINE

Base Information

• Chemical Name: 4'-(DIMETHYLAMINO)BENZYLIDENE-4-NITROANILINE
• CAS No.: 896-05-9
• Molecular Formula: C15H15 N3 O2
• Molecular Weight: 269.303
• Hs Code.: 2925290090
• Mol file: 896-05-9.mol

Synonyms:Aniline,N',N'-dimethyl-4-nitro-N,4'-methylidynedi- (6CI,7CI,8CI);N-[4-(Dimethylamino)benzylidene]-4-nitroaniline

Chemical Property of 4'-(DIMETHYLAMINO)BENZYLIDENE-4-NITROANILINE

Chemical Property:

• Vapor Pressure: 2.37E-08mmHg at 25°C
• Refractive Index: 1.582
• Boiling Point: 451.8°C at 760 mmHg
• Flash Point: 227°C
• PSA: 61.42000
• Density: 1.14g/cm³
• LogP: 3.93460

Purity/Quality:

98%,99%, ^*data from raw suppliers

4'-(Dimethylamino)benzylidene-4-nitroaniline ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4'-(DIMETHYLAMINO)BENZYLIDENE-4-NITROANILINE

There total 7 articles about 4'-(DIMETHYLAMINO)BENZYLIDENE-4-NITROANILINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

4-nitro-aniline (100-01-6,104810-17-5) + 4-dimethylamino-benzaldehyde (100-10-7) → N,N-dimethyl-4-((4-nitrophenylimino)methyl)aniline (896-05-9)

Guidance literature:

In neat(no solvent); at 110 ℃; for 0.0166667h; Microwave irradiation;

DOI:10.1002/jhet.604

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + 4,4'-bis(dimethylamino)benzhydrol (119-58-4) → N,N-dimethyl-4-((4-nitrophenylimino)methyl)aniline (896-05-9) + tris[4-(dimethylamino)phenyl]methane (603-48-5) + N,N-dimethyl-aniline (121-69-7,77733-26-7)

Guidance literature:

bei laengerem Erhitzen;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + N-(4,4'-bis-dimethylamino-benzhydryl)-4-nitro-aniline (43001-34-9) → N,N-dimethyl-4-((4-nitrophenylimino)methyl)aniline (896-05-9) + N,N-dimethyl-aniline (121-69-7,77733-26-7)

Guidance literature:

upstream raw materials:

4,4'-bis(dimethylamino)benzhydrol

4-nitro-aniline

4-dimethylamino-benzaldehyde

Hexafluoraceton-N-(p-nitrophenyl)-imin

Downstream raw materials:

N,N-dimethyl-4-{[(4-nitrophenyl)amino]methyl}aniline

[(4-dimethylamino-phenyl)-(4-nitro-phenylamino)-methyl]-phosphonic acid diisopropyl ester

Refernces

• 1、 Pagadala, Ramakanth,Meshram, Jyotsna S.,Chopde, Himani N.,Jetti, Venkateshwarlu,Udayini. "An expeditious one-pot synthesis of substituted phenylazetidin-2-ones in the presence of zeolite". experimental part. p. 1067 - 1072. Retrieved 2011/10/31.
• 2、 Neuvonen, Helmi,Neuvonen, Kari,Fueloep, Ferenc. "Substituent cross-interaction effects on the electronic character of the C=N bridging group in substituted benzylidene anilines - Models for molecular cores of mesogenic compounds. A 13C NMR study and comparison with theoretical results". . p. 3141 - 3148. Retrieved 2007/10/03.