PENTAFLUOROPHENYLMAGNESIUM BROMIDE

Base Information

Chemical Name:PENTAFLUOROPHENYLMAGNESIUM BROMIDE
CAS No.:879-05-0
Deprecated CAS:2271352-35-1
Molecular Formula:C6Br F5 Mg
Molecular Weight:271.267
Hs Code.:2931900090
European Community (EC) Number:628-260-6
DSSTox Substance ID:DTXSID1075438
Mol file:879-05-0.mol

Synonyms:Bromo(pentafluorophenyl)magnesium;Pentafluorophenylmagnesium bromide

Suppliers and Price of PENTAFLUOROPHENYLMAGNESIUM BROMIDE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Pentafluorophenylmagnesium bromide solution 0.5?M in diethyl ether
100 mL
$ 189.00

Sigma-Aldrich
Pentafluorophenylmagnesium bromide solution 0.5M in diethyl ether
100ml-a
$ 179.00

Rieke Metals
2,3,4,5,6-Pentafluorophenylmagnesiumbromide
50mL
$ 153.00

Total 13 raw suppliers

Chemical Property of PENTAFLUOROPHENYLMAGNESIUM BROMIDE

Chemical Property:

Boiling Point:34.6 °C
Flash Point:−35 °F
PSA：0.00000
Density:0.861 g/mL at 25 °C
LogP:-0.21210
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:0
Exact Mass:269.89540
Heavy Atom Count:13
Complexity:266

Purity/Quality:

98%,99%, ^*data from raw suppliers

Pentafluorophenylmagnesium bromide solution 0.5?M in diethyl ether ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F+,C
Statements: 12-14-19-22-34-66-67
Safety Statements: 26-36/37/39-43-45-16

MSDS Files:: SDS file from LookChem

Useful:

Chemical Classes:Metals -> Metals, Organic Compounds
Canonical SMILES:[C-]1=C(C(=C(C(=C1F)F)F)F)F.[Mg+2].[Br-]
Uses Employed in the synthesis of novel arsonic and arsinic acids as ligands for potential transition-metal ion extractants, and in the synthesis of polyfluoroaryl alkyl sulfides.

Technology Process of PENTAFLUOROPHENYLMAGNESIUM BROMIDE

There total 39 articles about PENTAFLUOROPHENYLMAGNESIUM BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 344-04-7
bromopentafluorobenzene

: 925-90-6
ethylmagnesium bromide

: 879-05-0
2,3,4,5,6-pentafluorophenylmagnesium bromide

Guidance literature:: In tetrahydrofuran; reaction at 0°C;;
DOI:10.1016/0022-328X(68)80092-0

Reference yield: 96.0%

: 392-56-3
Hexafluorobenzene

: 925-90-6
ethylmagnesium bromide

: 879-05-0
2,3,4,5,6-pentafluorophenylmagnesium bromide

Guidance literature:: iron(II) chloride; In tetrahydrofuran; reaction of 2 mol C2H5MgBr and 1 mol C6F6 at 0°C in presence of FeCl2 (molar fraction 0.02) within 0.5 hours;;
DOI:10.1016/S0022-328X(00)85394-2

Reference yield: 85.0%

: 363-72-4
Pentafluorobenzene

: 925-90-6
ethylmagnesium bromide

: 879-05-0
2,3,4,5,6-pentafluorophenylmagnesium bromide

Guidance literature:: In tetrahydrofuran; byproducts: C2H6; addition of C6F5H to C2H5MgBr in THF; formation of 86 % C2H6;;
DOI:10.1021/jo01031a067