8-Chloro-1-octene

Base Information

• Chemical Name: 8-Chloro-1-octene
• CAS No.: 871-90-9
• Molecular Formula: C8H15 Cl
• Molecular Weight: 146.66
• Hs Code.: 2903299090
• European Community (EC) Number: 807-609-8
• DSSTox Substance ID: DTXSID20462904
• Nikkaji Number: J599.554J
• Mol file: 871-90-9.mol

Synonyms:1-Chlorooct-7-ene;7-Octen-1-yl chloride; 8-Chlorooct-1-ene

Chemical Property of 8-Chloro-1-octene

Chemical Property:

• Vapor Pressure: 1.19mmHg at 25°C
• Refractive Index: 1.436
• Boiling Point: 180.9°C at 760 mmHg
• Flash Point: 59.1°C
• PSA: 0.00000
• Density: 0.877g/cm³
• LogP: 3.36170
• Storage Temp.: 2-8°C
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 146.0862282
• Heavy Atom Count: 9
• Complexity: 59.6

Purity/Quality:

97% ^*data from raw suppliers

8-Chlorooct-1-ene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCCCCCCl

Technology Process of 8-Chloro-1-octene

There total 9 articles about 8-Chloro-1-octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

oct-7-en-1-ol (13175-44-5) → 8-chloro-oct-1-ene (871-90-9)

Guidance literature:

With pyridine; thionyl chloride; In toluene; at 5 - 15 ℃; for 10h; Temperature; Reagent/catalyst;

Reference yield: 86.0%

1-bromo-5-chloropentane (54512-75-3) + allyl bromide (106-95-6) → 8-chloro-oct-1-ene (871-90-9)

Guidance literature:

allyl bromide; With magnesium; In diethyl ether; for 9h;

In tetrahydrofuran; at 45 - 65 ℃; for 3.16667h;

1-bromo-5-chloropentane; In tetrahydrofuran; at 50 - 60 ℃; for 1.5h;

DOI:10.15227/orgsyn.076.0221

Reference yield: 83.0%

1-bromo-5-chloropentane (54512-75-3) + allylmagnesium bromide (1730-25-2) → 8-chloro-oct-1-ene (871-90-9)

Guidance literature:

With dilithium tetrachlorocuprate; In tetrahydrofuran; at 0 ℃; for 0.5h;

DOI:10.1080/00397919408010156

upstream raw materials:

8-chloro-oct-1-yne

3-chloroprop-1-ene

1,5-dichloropentane

allylmagnesium bromide

Downstream raw materials:

8-iodo-oct-1-ene

8-chlorooctan-1-ol

4-(7-octenyloxy)benzoic acid

8-[p-(7-octenyloxy)benzoyl]amino-2-(5-tetrazolyl)-4-oxo-4H-1-benzopyran