(tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone

Base Information

Chemical Name:(tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone
CAS No.:154698-94-9
Molecular Formula:C₂₇H₃₂O₄Si
Molecular Weight:448.634
Hs Code.:

Synonyms:(tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone

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Chemical Property of (tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone

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Technology Process of (tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone

There total 3 articles about (tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 57234-27-2
1-(methoxymethoxy)-3-methylbenzene

: 154698-93-8
2-((tertbutyldiphenylsilyl)oxy)-N-methoxy-N-methylacetamide

: 154698-94-9
(tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone

Guidance literature:: With tert.-butyl lithium; In diethyl ether; hexane; at 0 ℃; 1.) 2 h, 2.) 1 h;
DOI:10.1021/jo00080a014

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 154698-94-9
(tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / imidazole, DMAP / dimethylformamide / 10 h / Ambient temperature

2: 97 percent / Me₃Al / CH₂Cl₂; hexane / 1.) -15 deg C, 30 min; room temp., 35 min, 2.) room temp., 2 h

3: 80 percent / t-BuLi / diethyl ether; hexane / 0 °C / 1.) 2 h, 2.) 1 h

With 1H-imidazole; dmap; trimethylaluminum; tert.-butyl lithium; In diethyl ether; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo00080a014

Reference yield:

: 154698-92-7
methyl 2-((tert-butyl(diphenyl)silyl)oxy)acetate

: 154698-94-9
(tert-Butyldiphenylsiloxy)methyl 2-<(methoxymethyl)oxy>-4-methylphenyl ketone

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / Me₃Al / CH₂Cl₂; hexane / 1.) -15 deg C, 30 min; room temp., 35 min, 2.) room temp., 2 h

2: 80 percent / t-BuLi / diethyl ether; hexane / 0 °C / 1.) 2 h, 2.) 1 h

With trimethylaluminum; tert.-butyl lithium; In diethyl ether; hexane; dichloromethane;
DOI:10.1021/jo00080a014