2,3,6,7,10,11-Hexamethoxytriphenylene

Base Information

• Chemical Name: 2,3,6,7,10,11-Hexamethoxytriphenylene
• CAS No.: 808-57-1
• Molecular Formula: C24H24O6
• Molecular Weight: 408.451
• Hs Code.: 29093090
• DSSTox Substance ID: DTXSID70404819
• Nikkaji Number: J584.217D
• Wikidata: Q72482118
• Mol file: 808-57-1.mol

Synonyms:2,3,6,7,10,11-Hexamethoxytriphenylene;808-57-1;C24H24O6;SCHEMBL1711296;YSSJ00704;DTXSID70404819;TXROZCSFVVIBFI-UHFFFAOYSA-N;MFCD00075571;AKOS015901614;CS-W009387;SB67046;DS-18496;2,3,6,7,10.11-Hexamethoxytriphenylene;2,3,6,7,10,11-hexamethoxy triphenylene;FT-0660749;H0898;C76589;A864639

Chemical Property of 2,3,6,7,10,11-Hexamethoxytriphenylene

Chemical Property:

• Vapor Pressure: 8.81E-13mmHg at 25°C
• Melting Point: 310-317℃
• Refractive Index: 1.632
• Boiling Point: 578.6 °C at 760 mmHg
• Flash Point: 235.8 °C
• PSA: 55.38000
• Density: 1.216 g/cm³
• LogP: 5.19780
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 408.15728848
• Heavy Atom Count: 30
• Complexity: 434

Purity/Quality:

98%,99%, ^*data from raw suppliers

2,3,6,7,10,11-Hexamethoxytriphenylene ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C(C=C2C(=C1)C3=CC(=C(C=C3C4=CC(=C(C=C24)OC)OC)OC)OC)OC

Technology Process of 2,3,6,7,10,11-Hexamethoxytriphenylene

There total 20 articles about 2,3,6,7,10,11-Hexamethoxytriphenylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

3,3'',4,4',4'',5'-hexamethoxy-o-terphenyl (2319-91-7) → 2,3,6,7,10,11-hexamethoxytriphenylene (808-57-1)

Guidance literature:

With trifluorormethanesulfonic acid; 5% Pd/Al2O3; oxygen; In 2,2,2-trifluoroethanol; at 20 ℃;

DOI:10.1002/adsc.201600584

Reference yield: 97.0%

1,2-dimethoxybenzene (91-16-7) → 2,3,6,7,10,11-hexamethoxytriphenylene (808-57-1)

Guidance literature:

With iron(III) chloride; In dichloromethane;

DOI:10.1002/anie.201002369

Reference yield: 65.0%

1,2-dimethoxybenzene (91-16-7) → 2,3,6,7,10,11-hexamethoxytriphenylene (808-57-1) + 2,3-dimethoxy-6,7,10,11-tetrahexyloxytriphenylene (152634-10-1)

Guidance literature:

With iron(III) chloride; 3,3',4,4'-tetrahexyloxybiphenyl; In dichloromethane; for 1h; Ambient temperature;

DOI:10.1039/c39940000465

upstream raw materials:

Methylenedioxybenzene

1,2-dimethoxybenzene

benzo-1,4-dioxane

2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin

Downstream raw materials:

2,3,6,7,10,11-hexamethoxy-4,8,12-tri(4-bromophenyl)-1,5,9-triazocoronene

2,3,6,7,10,11-hexakis(pentyloxy)triphenylene

2,3,6,7,10,11-hexakis(hexyloxy)triphenylene

2,3,6,7,10,11-hexahydroxytriphenylene

Refernces

• 1、 An, Shujie,Liu, Qiancai,Ma, Li,Tang, Guofeng,Zhong, Yaling. "Novel Large π-Conjugated Coronene-Based Molecules: Diaryl-Substituted 1,2,7,8,13,14-Hexamethoxytribenzo[a,g,m]coronenes". . p. 1779 - 1783. Retrieved 2020.
• 2、 K, Swamynathan,Sasidharan, Sreeja,V.A, Raghunathan,Kumar, Sandeep. "Mesomorphic triphenylene polyanion-surfactant complexes". . . Retrieved 2020/12/02.
• 3、 Liu, Yurong,Li, Wei,Zhou, Xuan,Wong, Wai-Yeung,Yu, Zhen-Qiang. "Highly ordered smectic structures of disc-rod luminescent liquid crystals: The role of the tolane group". supporting information. p. 3555 - 3561. Retrieved 2021/03/26.