3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal

Base Information

Chemical Name:3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal
CAS No.:306968-34-3
Molecular Formula:C₄₀H₄₈O₇
Molecular Weight:640.817
Hs Code.:

Synonyms:3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal

Suppliers and Price of 3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal

There total 3 articles about 3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-24-1
trimethylaluminum

: 261713-59-1
2,3,4,6-tetra-O-benzyl-5',5'-dimethylspiro[1,5-anhydro-D-glucitol-1,2'-[1,3]dioxane]

: 306968-34-3
3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal

Guidance literature:: In hexane; dichloromethane; at 20 ℃;
DOI:10.1016/S0040-4020(00)00621-9

Reference yield:

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 306968-34-3
3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / TMSOMe; TMSOTf / toluene / 2 h / 20 °C

2: CH₂Cl₂ / 2 h / 20 °C

With Trimethylmethoxysilane; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; toluene; 1: Cycloaddition / 2: Ring cleavage;
DOI:10.1021/ol9913035

Reference yield:

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 306968-34-3
3,4,5,7-tetra-O-benzyl-1-deoxy-D-gluco-2-heptulose 2,2-dimethylpropane-1,3-diyl acetal

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / TMSOMe; TMSOTf / toluene / 1 h / 20 °C

2: CH₂Cl₂; hexane / 20 °C

With Trimethylmethoxysilane; trimethylsilyl trifluoromethanesulfonate; In hexane; dichloromethane; toluene;
DOI:10.1016/S0040-4020(00)00621-9