1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide

Base Information

Chemical Name:1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide
CAS No.:270062-18-5
Molecular Formula:C₄₁H₄₃NO₇
Molecular Weight:661.795
Hs Code.:

Synonyms:1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide

Suppliers and Price of 1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide

There total 1 articles about 1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 13096-62-3
(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one

: 622-33-3
N-benzyloxyamine

: 270062-18-5
1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide

Guidance literature:: With trimethylaluminum; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/ja992808t

Reference yield: 71.0%

: 270062-18-5
1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide

: 270062-25-4
2N-benzyloxy-3,4,5-tris(benzyloxy)-6-benzyloxymethyl-(3R,4S,5R,6S)-tetrahydro-2H-pyran-2-imine

: 1,3,4,5-tetrakis(benzyloxy)-6-benzyloxymethyl-(3R,4S,5R,6S)-tetrahydropyridin-2(1H)-one

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 20 ℃; for 0.166667h;
DOI:10.1021/ja992808t

Reference yield:

: 270062-18-5
1N-benzyloxy-2,3,4,6-tetrakis(benzyloxy)-5-hydroxy-(2R,3S,4R,5R)-hexanamide

: 4132-28-9,4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5
2,3,4,6-tetra-O-benzyl-L-idopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: 71 percent / PPh₃; DEAD / tetrahydrofuran / 0.17 h / 20 °C

2: 97 percent / p-toluenesulfonic acid monohydrate / acetone / 4.5 h / 20 °C

3: 99 percent / DIBAL-H / CH₂Cl₂; hexane / 0.33 h / -78 °C

With diisobutylaluminium hydride; toluene-4-sulfonic acid; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; hexane; dichloromethane; acetone; 1: Cyclization / 2: Deoximation / 3: Reduction;
DOI:10.1021/ja992808t