C₂₈H₄₇NO₅Si

Base Information

Chemical Name:C₂₈H₄₇NO₅Si
CAS No.:1610888-01-1
Molecular Formula:C₂₈H₄₇NO₅Si
Molecular Weight:505.77
Hs Code.:

C<sub>28</sub>H<sub>47</sub>NO<sub>5</sub>Si

Synonyms:C₂₈H₄₇NO₅Si

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Chemical Property of C₂₈H₄₇NO₅Si

Chemical Property:

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Technology Process of C₂₈H₄₇NO₅Si

There total 12 articles about C₂₈H₄₇NO₅Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10416-59-8
N,O-bis-(trimethylsilyl)-acetamide

: 1610888-00-0
(4S,5S,7R,8R,E)-7-(benzyloxy)-5-[(tert-butyldimethylsilyl)oxy]-8-methoxy-2,4-dimethyldeca-2,9-dienal

: 1610888-01-1
C₂₈H₄₇NO₅Si

Guidance literature:: N,O-bis-(trimethylsilyl)-acetamide; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

(4S,5S,7R,8R,E)-7-(benzyloxy)-5-[(tert-butyldimethylsilyl)oxy]-8-methoxy-2,4-dimethyldeca-2,9-dienal; In tetrahydrofuran; at -105 - -78 ℃; for 2h; Inert atmosphere;
DOI:10.1021/ol5011278

Reference yield:

: 1610887-86-9
1-{[(3R,4R)-3-(benzyloxy)-4-methoxyhex-5-enyloxy]methyl}-4-methoxybenzene

: 1610888-01-1
C₂₈H₄₇NO₅Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: water; 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1.5 h / 0 °C / Inert atmosphere

2.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 1.25 h / -78 - -45 °C / Inert atmosphere

2.2: 20 °C / Inert atmosphere

3.1: triethylamine; di-n-butylboryl trifluoromethanesulfonate / dichloromethane / 2 h / -78 - 0 °C / Inert atmosphere

3.2: 12 h / -78 °C / Inert atmosphere

4.1: 2,6-dimethylpyridine; t-butyldimethylsiyl triflate / dichloromethane / 12 h / -78 - 20 °C / Inert atmosphere

5.1: lithium borohydride / methanol; diethyl ether / 12 h / 0 °C / Inert atmosphere

6.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0 °C / Inert atmosphere

7.1: dichloromethane / 55 °C / Inert atmosphere

8.1: diisobutylaluminium hydride / dichloromethane; hexane / 0.58 h / -78 °C / Inert atmosphere

8.2: 12 h / 20 °C / Inert atmosphere

9.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

10.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

10.2: 2 h / -105 - -78 °C / Inert atmosphere

With 2,6-dimethylpyridine; lithium borohydride; n-butyllithium; oxalyl dichloride; di-n-butylboryl trifluoromethanesulfonate; t-butyldimethylsiyl triflate; water; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; 2.1: |Swern Oxidation / 2.2: |Swern Oxidation / 3.1: |Aldol Addition / 3.2: |Aldol Addition / 7.1: |Wittig Olefination / 10.2: |Aldol Condensation;
DOI:10.1021/ol5011278

Reference yield:

: 1610887-87-0
(3R,4R)-3-(benzyloxy)-4-methoxyhex-5-ene-1-ol

: 1610888-01-1
C₂₈H₄₇NO₅Si

Guidance literature:: Multi-step reaction with 6 steps

1.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 1.25 h / -78 - -45 °C / Inert atmosphere

1.2: 20 °C / Inert atmosphere

2.1: titanium(IV) trichloride isopropoxide / dichloromethane / 1 h / -78 °C / Inert atmosphere

2.2: 48 h / -50 °C / Inert atmosphere

2.3: 24 h / 20 °C / Inert atmosphere

3.1: 2,6-dimethylpyridine / dichloromethane / 12 h / -78 - 20 °C / Inert atmosphere

4.1: lithium borohydride / methanol; diethyl ether / 12 h / 0 °C / Inert atmosphere

5.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

6.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

6.2: 2 h / -105 - -78 °C / Inert atmosphere

With 2,6-dimethylpyridine; lithium borohydride; n-butyllithium; oxalyl dichloride; titanium(IV) trichloride isopropoxide; sodium hydrogencarbonate; Dess-Martin periodane; dimethyl sulfoxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; 1.1: |Swern Oxidation / 1.2: |Swern Oxidation / 6.2: |Aldol Condensation;
DOI:10.1021/ol5011278