(η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride

Base Information

• Chemical Name: (η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride
• CAS No.: 166033-75-6
• Molecular Formula: C₁₂H₂₁Cl₃SiTi
• Molecular Weight: 347.623
• Mol file: 166033-75-6.mol

Synonyms:(η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride

Chemical Property of (η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride

There total 3 articles about (η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

[(C5Me4SiMe3)4Ti4(μ3-NH)2(μ3-N)2] + 4-iodobenzoic acid chloride (1711-02-0) → (η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride (166033-75-6) + 4-iodobenzonitrile (3058-39-7)

Guidance literature:

In benzene; at 60 ℃; for 12h; Schlenk technique; Glovebox; Inert atmosphere;

DOI:10.1002/anie.201607426

Reference yield: 83.0%

hydrogenchloride (7647-01-0,15364-23-5) + [(C5Me4SiMe3)4Ti4(μ3-NH)2(μ3-N)2] + 4-methyl-benzoyl chloride (874-60-2) → (η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride (166033-75-6) + para-methylbenzonitrile (104-85-8)

Guidance literature:

In diethyl ether; Inert atmosphere;

DOI:10.1002/anie.201607426

Reference yield: 83.0%

hydrogenchloride (7647-01-0,15364-23-5) + [(C5Me4SiMe3)4Ti4(μ3-15NH)2(μ3-15N)2] + p-tert-butyl benzoyl chloride (1710-98-1) → (η-5-trimethylsilyltetramethylcyclopentadienyl)titanium trichloride (166033-75-6) + C11H13(15)N

Guidance literature:

In diethyl ether; Glovebox; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201607426

upstream raw materials:

hydrogenchloride

4-methyl-benzoyl chloride

p-tert-butyl benzoyl chloride

4-iodobenzoic acid chloride