(pentamethylphenyl)nitromethane

Base Information

• Chemical Name: (pentamethylphenyl)nitromethane
• CAS No.: 29328-77-6
• Molecular Formula: C₁₂H₁₇NO₂
• Molecular Weight: 207.272
• Mol file: 29328-77-6.mol

Synonyms:(pentamethylphenyl)nitromethane

Chemical Property of (pentamethylphenyl)nitromethane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (pentamethylphenyl)nitromethane

There total 16 articles about (pentamethylphenyl)nitromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

Hexamethylbenzene (87-85-4) → (pentamethylphenyl)nitromethane (29328-77-6) + 1,2-Bis(nitromethyl)-3,4,5,6-tetramethylbenzene (42154-08-5)

Guidance literature:

With tetranitromethane; lithium perchlorate; In acetonitrile; for 8h; Irradiation;

DOI:10.1021/ja00188a048

Reference yield: 51.0%

Hexamethylbenzene (87-85-4) → (pentamethylphenyl)nitromethane (29328-77-6) + pentamethylbenzyl nitrate (19405-90-4)

Guidance literature:

With dinitrogen tetraoxide; In dichloromethane; at 0 ℃; for 1h;

DOI:10.1021/jo00091a018

Reference yield:

Hexamethylbenzene (87-85-4) → pentamethylbenzaldehyde (17432-38-1) + (pentamethylphenyl)nitromethane (29328-77-6) + 2,3,4,5,6-pentamethylbenzyl alcohol (484-66-2)

Guidance literature:

With 2,6-di-tert-butyl-4-methylpyridine; oxygen; nitrosonium tetrafluoroborate; In dichloromethane; at 3 ℃; for 2h;

DOI:10.1021/jo00268a036

upstream raw materials:

Hexamethylbenzene

2,3,4,5,6-pentamethylbenzyl chloride

tetranitromethane

trimethyl((2,3,4,5,6-pentamethylphenyl)methyl)silane