methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate

Base Information

Chemical Name:methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate
CAS No.:1352813-97-8
Molecular Formula:C₂₇H₂₆F₃NO₁₁
Molecular Weight:597.499
Hs Code.:

Synonyms:methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate

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Chemical Property of methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate

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Technology Process of methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate

There total 1 articles about methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 6974-29-4
N-(2-hydroxyethyl)-2,2,2-trifluoroacetamide

: methyl (3-O-acetyl-2,4-di-O-benzoyl-α-D-glucopyranosyl trichloroacetamidate)uronate

: 1352813-97-8
methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate

Guidance literature:: N-(2-hydroxyethyl)-2,2,2-trifluoroacetamide; methyl (3-O-acetyl-2,4-di-O-benzoyl-α-D-glucopyranosyl trichloroacetamidate)uronate; With boron trifluoride diethyl etherate; In dichloromethane; for 2h;

With pyridine; In dichloromethane;
DOI:10.1021/ja2083015

Reference yield: 84.0%

: 1352813-97-8
methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate

: 1352813-98-9
methyl (2-trifluoroacetamidoethyl 2,4-di-O-benzoyl-β-D-glucopyranosid)uronate

Guidance literature:: With hydrogenchloride; In methanol; at 20 ℃; for 30h;
DOI:10.1021/ja2083015

Reference yield:

: 1352813-97-8
methyl (2-trifluoroacetamidoethyl 3-O-acetyl-2,4-di-O-benzoyl-β-D-glucopyranosid)uronate

: 1352813-99-0
methyl (2-trifluoroacetamidoethyl 2,4-di-O-benzoyl-3-O-sulfo-β-D-glucopyranosid)uronate sodium salt

Guidance literature:: Multi-step reaction with 2 steps

1.1: hydrogenchloride / methanol / 30 h / 20 °C

2.1: pyridine; sulfur trioxide pyridine complex / 4 h / 20 °C

2.2: Amberlite IRA-120 Na⁺ resin / 0.5 h

With pyridine; hydrogenchloride; sulfur trioxide pyridine complex; In methanol;
DOI:10.1021/ja2083015