(2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol

Base Information

Chemical Name:(2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol
CAS No.:934497-75-3
Molecular Formula:C₁₈H₂₆N₄O₄S
Molecular Weight:394.495
Hs Code.:

Synonyms:(2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol

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Chemical Property of (2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol

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Technology Process of (2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol

There total 7 articles about (2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 934497-74-2
(3S,4S,5E,8S)-4,8-dimethyl-9-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]non-5-en-3-ol

: 934497-75-3
(2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol

Guidance literature:: With potassium peroxymonosulfate; Shi's ketone; sodium tetraborate decahydrate; potassium carbonate; In acetonitrile; at 0 ℃; pH=9;
DOI:10.1021/ol301886g

Reference yield:

: 934497-74-2
(3S,4S,5E,8S)-4,8-dimethyl-9-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]non-5-en-3-ol

: 934497-75-3
(2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol

: 934497-76-4
C₁₈H₂₄N₄O₄S

Guidance literature:: With borax; Oxone; potassium carbonate; 1,2,4,5-di-O-isopropylidene-D-erythro-2,3-hexodiuro-2,6-pyranose; In water; acetonitrile; at 0 ℃; for 2h;

Reference yield:

: 1399680-07-9
(2S,6S,7S,E)-2,6-dimethyl-7-((triethylsilyl)oxy)non-4-en-1-yl methanesulfonate

: 934497-75-3
(2R,3S)-2-((2R,3R)-3-{(2S)-2-methyl-3-[(1-phenyl-1H-tetrazol-5-yl)sulfonyl]propyl}oxiran-2-yl)pentan-3-ol

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / tetrahydrofuran / 60 °C / Inert atmosphere

2: hexaammonium heptamolybdate tetrahydrate; dihydrogen peroxide / ethanol

3: potassium carbonate; potassium peroxymonosulfate; sodium tetraborate decahydrate; Shi's ketone / acetonitrile / 0 °C / pH 9

With potassium peroxymonosulfate; Shi's ketone; sodium tetraborate decahydrate; hexaammonium heptamolybdate tetrahydrate; dihydrogen peroxide; sodium hydride; potassium carbonate; In tetrahydrofuran; ethanol; acetonitrile;
DOI:10.1021/ol301886g