(S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene

Base Information

Chemical Name:(S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene
CAS No.:1395097-89-8
Molecular Formula:C₁₈H₂₈O₃
Molecular Weight:292.419
Hs Code.:

Synonyms:(S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene

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Technology Process of (S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene

There total 6 articles about (S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1395097-88-7
C₁₁H₂₂O₃

: 100-39-0
benzyl bromide

: 1395097-89-8
(S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene

Guidance literature:: C₁₁H₂₂O₃; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.5h; Inert atmosphere;

benzyl bromide; In N,N-dimethyl-formamide; oil; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1055/s-0031-1291143

Reference yield:

: 1395097-87-6
(S,E)-ethyl 3-ethyl-3-((methoxymethoxy)methyl)hex-4-enoate

: 1395097-89-8
(S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.67 h / 0 °C / Inert atmosphere

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 °C / Inert atmosphere

2.2: 2 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil;
DOI:10.1055/s-0031-1291143

Reference yield:

: 1395097-83-2
(S,E)-ethyl 4-((tert-butyldimethylsilyl)oxy)-2-ethylpent-2-enoate

: 1395097-89-8
(S,E)-(((3-ethyl-3-((methoxymethoxy)methyl)hex-4-en-1-yl)oxy)methyl)benzene

Guidance literature:: Multi-step reaction with 6 steps

1.1: diisobutylaluminium hydride / dichloromethane; toluene / 1.17 h / -78 °C / Inert atmosphere

2.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 6 h / 0 - 20 °C / Inert atmosphere

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 6 h / 20 °C / Inert atmosphere

4.1: propionic acid / toluene / 15 h / 120 °C / Inert atmosphere

5.1: lithium aluminium tetrahydride / tetrahydrofuran / 0.67 h / 0 °C / Inert atmosphere

6.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 0 °C / Inert atmosphere

6.2: 2 h / 20 °C / Inert atmosphere

With lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; propionic acid; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene; mineral oil; 4.1: Johnson-Claisen rearrangement;
DOI:10.1055/s-0031-1291143