(Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene

Base Information

• Chemical Name: (Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene
• CAS No.: 78479-61-5
• Molecular Formula: C₂₈H₂₀I₂
• Molecular Weight: 610.276
• Mol file: 78479-61-5.mol

Synonyms:(Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene

Chemical Property of (Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene

There total 2 articles about (Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diphenyl acetylene (501-65-5) → (Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene (78479-61-5)

Guidance literature:

With n-butyllithium; zirconocene dichloride; iodine;

DOI:10.1016/S0040-4039(00)84653-5

Reference yield:

2,3,4,5-Tetraphenyliodolium Iodide Hydrate (34143-19-6) → (Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene (78479-61-5)

Guidance literature:

at 140 ℃; Thermodynamic data; in CH₂CL₂ solution at room temperature; enthalpy of isomerization;

DOI:10.1021/jo00333a029

Reference yield: 93.0%

(Z,Z)-1,4-diiodo-1,2,3,4-tetraphenyl-1,3-butadiene (78479-61-5) → tetraphenylthiophene (1884-68-0)

Guidance literature:

With copper(l) iodide; potassium sulfide; In acetonitrile; at 20 ℃; Heating;

DOI:10.1021/ol101619s

upstream raw materials:

2,3,4,5-Tetraphenyliodolium Iodide Hydrate

diphenyl acetylene

Downstream raw materials:

5-ioda-1,2,3,4-tetraphenylbicyclo<2.1.0>pentenium hexachloroantimonate

2,3,4,5-tetraphenylcyclopenta-2,4-dienone

tetraphenylthiophene

1-(4-methylphenyl)-2,3,4,5-tetraphenyl-1H-pyrrole