tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

Base Information

Chemical Name:tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate
CAS No.:132639-37-3
Molecular Formula:C₁₉H₂₅Br₂NO₃
Molecular Weight:475.22
Hs Code.:

Synonyms:tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

Suppliers and Price of tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

There total 4 articles about tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

: 74-83-9
methyl bromide

: 132639-34-0
tert-Butyl (E,4S)-2,2-dimethyl-4-(2'-phenylvinyl)-3-oxazolidine-3-carboxylate

: 132639-37-3
tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

: 132697-89-3
tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

Guidance literature:: With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; In ethanol; benzene; for 48h; Ambient temperature;
DOI:10.1016/S0040-4020(01)88208-9

Reference yield:

: 1449-46-3
benzyltriphenylphosphonium bromide

: 132639-37-3
tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) n-BuLi / 1) hexane, 30 min, 2) 2 h

2: 74 percent / aq. NaOH (50percent), benzyltriethylammonium chloride / benzene; ethanol / 48 h / Ambient temperature

With sodium hydroxide; n-butyllithium; N-benzyl-N,N,N-triethylammonium chloride; In ethanol; benzene;
DOI:10.1016/S0040-4020(01)88208-9

Reference yield:

: 95715-87-0
(R)-3-tert-butoxycarbonyl-4-formyl-2,2-dimethyloxazolidine

: 132639-37-3
tert-butyl (E)-4-(2',2'-dibromo-3'-phenylcyclopropyl)-2,2-dimethyl-3-oxazolidinecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) n-BuLi / 1) hexane, 30 min, 2) 2 h

2: 74 percent / aq. NaOH (50percent), benzyltriethylammonium chloride / benzene; ethanol / 48 h / Ambient temperature

With sodium hydroxide; n-butyllithium; N-benzyl-N,N,N-triethylammonium chloride; In ethanol; benzene;
DOI:10.1016/S0040-4020(01)88208-9