7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

Base Information

Chemical Name:7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone
CAS No.:849338-78-9
Molecular Formula:C₃₂H₄₂O₁₂
Molecular Weight:618.678
Hs Code.:

Synonyms:7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

Suppliers and Price of 7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

There total 13 articles about 7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 861216-48-0
tert-butyl 2-methylbut-3-en-2-yl carbonate

: 849338-74-5
5′-hydroxy-7,2′,4′-tris(2-methoxyethoxymethoxy)isoflavone

: 849338-78-9
7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1248/CPB.C20-00346

Reference yield: 88.0%

: 849338-77-8
7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylpropargyloxy)isoflavone

: 849338-78-9
7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

Guidance literature:: With quinoline; hydrogen; Lindlar's catalyst; In ethanol; at 20 ℃; for 0.666667h; ambient pressure;
DOI:10.1039/b414955f

Reference yield:

: 849338-69-8
3-bromo-7-(2-methoxyethoxymethoxy)chromone

: 849338-78-9
7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

Guidance literature:: Multi-step reaction with 4 steps

1.1: 89 percent / aq. Na₂CO₃; tetrabutylammonium bromide / Pd(PPh₃)4 / benzene / 3 h / 80 °C

2.1: m-CPBA; NaHCO₃ / CH₂Cl₂ / 0.42 h / -10 °C

2.2: 80 percent / KOH / methanol / 0.5 h / 20 °C / pH 9 - 10

3.1: CuCl₂; DBU / acetonitrile / 0.25 h / cooling

3.2: 70 percent / acetonitrile / 6.5 h / 20 °C

4.1: 88 percent / H₂; quinoline / Lindlar's catalyst / ethanol / 0.67 h / 20 °C / ambient pressure

With quinoline; tetrabutylammomium bromide; hydrogen; sodium hydrogencarbonate; sodium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; copper dichloride; Lindlar's catalyst; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In ethanol; dichloromethane; acetonitrile; benzene; 1.1: Suzuki-Miyaura coupling / 2.1: Baeyer-Villiger oxidation;
DOI:10.1039/b414955f