5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone

Base Information

Chemical Name:5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone
CAS No.:849338-76-7
Molecular Formula:C₃₂H₄₂O₁₂
Molecular Weight:618.678
Hs Code.:

Synonyms:5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone

Chemical Property:

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Technology Process of 5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone

There total 14 articles about 5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 849338-78-9
7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(1,1-dimethylallyloxy)isoflavone

: 849338-76-7
5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone

Guidance literature:: With N,N-diethylaniline; at 180 ℃; for 0.5h;
DOI:10.1039/b414955f

Reference yield: 4.0%

: 849338-75-6
7,2',4'-tris(2-methoxyethoxymethoxy)-5'-(3,3-dimethylallyloxy)isoflavone

: 849338-74-5
5′-hydroxy-7,2′,4′-tris(2-methoxyethoxymethoxy)isoflavone

: 849338-76-7
5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone

Guidance literature:: With Montmorillonite K₁₀; In dichloromethane; at 0 ℃; for 48h;
DOI:10.1039/b414955f

Reference yield:

: 849338-68-7
(E)-1-[2-hydroxy-4-(2-methoxyethoxymethoxy)phenyl]-3-dimethylaminopropen-1-one

: 849338-76-7
5'-hydroxy-7,2',4'-tris(2-methoxyethoxymethoxy)-6'-(3,3-dimethylallyl)isoflavone

Guidance literature:: Multi-step reaction with 6 steps

1.1: 64 percent / N-bromosuccinimide; silica gel / CHCl₃ / 0.5 h / 0 °C

2.1: 89 percent / aq. Na₂CO₃; tetrabutylammonium bromide / Pd(PPh₃)4 / benzene / 3 h / 80 °C

3.1: m-CPBA; NaHCO₃ / CH₂Cl₂ / 0.42 h / -10 °C

3.2: 80 percent / KOH / methanol / 0.5 h / 20 °C / pH 9 - 10

4.1: CuCl₂; DBU / acetonitrile / 0.25 h / cooling

4.2: 70 percent / acetonitrile / 6.5 h / 20 °C

5.1: 88 percent / H₂; quinoline / Lindlar's catalyst / ethanol / 0.67 h / 20 °C / ambient pressure

6.1: 89 percent / N,N-diethylaniline / 0.5 h / 180 °C

With quinoline; N-Bromosuccinimide; tetrabutylammomium bromide; hydrogen; silica gel; sodium hydrogencarbonate; sodium carbonate; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; N,N-diethylaniline; copper dichloride; Lindlar's catalyst; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In ethanol; dichloromethane; chloroform; acetonitrile; benzene; 2.1: Suzuki-Miyaura coupling / 3.1: Baeyer-Villiger oxidation / 6.1: Claisen rearrangement;
DOI:10.1039/b414955f