5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene

Base Information

• Chemical Name: 5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene
• CAS No.: 190371-89-2
• Molecular Formula: C₆₂H₇₆I₂O₆
• Molecular Weight: 1171.09
• Mol file: 190371-89-2.mol

Synonyms:5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene

Chemical Property of 5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene

There total 1 articles about 5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.3%

2',5'-Bis-(4-dodecyloxy-phenylethynyl)-2,5,2'',5''-tetramethoxy-[1,1';4',1'']terphenyl (190371-84-7) → 5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene (190371-89-2)

Guidance literature:

With trifluorormethanesulfonic acid; [bis(pyridine)iodine]⁺ tetrafluoroborate; In dichloromethane; at -40 - 10 ℃;

DOI:10.1021/ja00096a056

Reference yield: 99.0%

5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene (190371-89-2) → 5,12-Bis-(4-dodecyloxy-phenyl)-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene

Guidance literature:

With sec.-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.0833333h;

DOI:10.1021/ja9642673

Reference yield: 95.0%

4-methoxyphenylboronic acid (5720-07-0) + 5,12-Bis-(4-dodecyloxy-phenyl)-6,13-diiodo-1,4,8,11-tetramethoxy-dibenzo[a,h]anthracene (190371-89-2) → 5,12-Bis-(4-dodecyloxy-phenyl)-1,4,8,11-tetramethoxy-6,13-bis-(4-methoxy-phenyl)-dibenzo[a,h]anthracene

Guidance literature:

With potassium hydroxide; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenylphosphine; In water; nitrobenzene; at 95 ℃; for 14h;

DOI:10.1021/jo9721251

upstream raw materials:

2',5'-Bis-(4-dodecyloxy-phenylethynyl)-2,5,2'',5''-tetramethoxy-[1,1';4',1'']terphenyl